[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride

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Catalog Number
ACM134524848
Product Name
[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
CAS
134524-84-8
Category
Ruthenium series catalysts
Synonyms
(R)-[2,2 inverted exclamation marka-Bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl]dichlororuthenium; C44H34Cl2P2Ru; DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-; KS-00000HO2; Dichloro [(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphathyl] ruthenium(II); [R-(R*, R*)]-7-[2-(4-Fluorophenyl)-5-(1-methylethyl)-3-phenyl-4-(phenylaminocarbonyl)-1H-pyrrol-1-yl]-3,5-dihydroxy-heptanoic acid calcium salt; (R)-[1,1 inverted exclamation marka-Binaphthalene]-2,2 inverted exclamation marka-diylbis[diphenylphosphine]ruthenium complex; 134524-84-8; ST24030314; [(R)-[1,1 inverted exclamation marka-Binaphthalene]-2,2 inverted exclamation marka-diylbis[diphenylphosphine-|EP]]dichloro-ruthenium;
IUPAC Name
dichlororuthenium;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;
Molecular Weight
794.658g/mol
Molecular Formula
C44H32Cl2P2Ru;
Canonical SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ru]Cl;
InChI
InChI=1S/C44H32P2.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2;
InChI Key
YEKBVMDAGDTOQB-UHFFFAOYSA-L;
Application
Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.

Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.
Complexity
800
Covalently-Bonded Unit Count
2
Exact Mass
794.04g/mol
Heavy Atom Count
49
Monoisotopic Mass
794.04g/mol
Rotatable Bond Count
7
Topological Polar Surface Area
0A^2
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