(S)-(-)-TolBINAP

• Catalog Number: ACM100165886
• Product Name: (S)-(-)-TolBINAP
• CAS: 100165-88-6
• Category: Heterocyclic Organic Compound
• IUPAC Name: [1-[2-bis(4-methylphenyl)phosphanylnaphthalen-1-yl]naphthalen-2-yl]-bis(4-methylphenyl)phosphane
• Molecular Weight: 678.796g/mol
• Molecular Formula: C48H40P2
• Canonical SMILES: CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=C(C=C7)C)C8=CC=C(C=C8)C
• InChI: InChI=1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3
• InChI Key: IOPQYDKQISFMJI-UHFFFAOYSA-N
• Application: Useful ligand for palladium-catalyzed carbon-oxygen bond formation.; ; Ligand for palladium-catalyzed α-arylation of ketones.; ; Ligand for Cu-catalyzed asymmetric conjugate reduction.; ; Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.; ; Enantioselective conjugate reduction of lactones and lactams.; ; Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.; ; Catalytic Aldol reaction to ketones.; ; Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.; ; Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.; ; Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.; ; Rhodium-catalyzed cross cyclotrimerization.
• Complexity: 897
• Covalently-Bonded Unit Count: 1
• Exact Mass: 678.261g/mol
• Heavy Atom Count: 50
• Monoisotopic Mass: 678.261g/mol
• Rotatable Bond Count: 7
• Topological Polar Surface Area: 0A^2