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Catalog Number
ACM555248
Product Name
Lithium phenoxide
Structure
CAS
555-24-8
Synonyms
LITHIUM PHENOXIDE;lithium phenoxide solution;LITHIUM PHENOXIDE, 1.0M SOLUTION IN TETR AHYDROFURAN;LITHIUM PHENOXIDE SOLUTION, ~1 M IN THF;phenol lithium salt;(Lithiooxy)benzene;Phenoxylithium;Lithium phenoxide solution,Phenol lithium salt
EC Number
209-086-6
IUPAC Name
lithium phenoxide
Molecular Formula
C6H5LiO
Molecular Weight
100.04
Exact Mass
100.05000
Boiling Point
181.8ºC at 760 mmHg
Flash Point
72.5ºC
Density
0.92 g/mL at 20ºC
Appearance
brown liquid
SMILES
[Li+].C1=CC=C(C=C1)[O-]
InChI Key
XAVQZBGEXVFCJI-UHFFFAOYSA-M
H-Bond Donor
0
H-Bond Acceptor
1
Safty Description
16-26-36/37/39-45
Hazard Statements
F: Flammable;C: Corrosive;
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1 Influence of alkali metal cations upon the Kolbe-Schmitt reaction mechanism.

Marković Z1, Marković S, Begović N.

J Chem Inf Model. 2006 Sep-Oct;46(5):1957-64.

The mechanisms of the carboxylations of lithium, potassium, rubidium, and cesium phenoxides are investigated by means of the DFT method with the LANL2DZ basis set. It is shown that the reactions of all alkali metal phenoxides with carbon dioxide occur via very similar reaction mechanisms. The reactions can proceed in the ortho and para positions. The exception is lithium phenoxide which yields only ... Read More

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA