CAS
193629-39-9 Purity
96%
193629-39-9 Purity
96%
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TRANS-4-DECENE
CAS
19398-89-1
Catalog Number
ACM19398891
Category
Main Products
Molecular Weight
140.27
Molecular Formula
C10H20
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Trans-4-decene for Pd catalyst hydrogenation studies
Fernández, María B., et al. Journal of Molecular Catalysis A: Chemical 237.1-2 (2005): 67-79.
The hydrogenation of sunflower oil over a supported Pd catalyst was studied. The adsorption of oleic acid on the Pd surface was modeled. The metal catalyst was represented by three low refractive index planes, while the oil was represented by cis-4-decene. In addition, two different mechanisms for the cis/trans isomerization and complete hydrogenation of oleic acid were investigated. Conformational studies were performed on the trans-4-decene model and all subsequent reaction structures. Theoretical studies showed that the selected mechanism is energetically possible on the Pd plane, but the monoyne-mediated mechanism is more exothermic.
On the subject of product adsorption, the following order of desorption was observed: decane > cis-4-decene (-3.7 eV) > trans-4-decene (-6.9 eV) All energies refer to decane. In comparison, the adsorption of trans-decene is preferred. It can be concluded that decane is easily desorbed once the second H is added.
Trans-4-decene was used for hydrogenation studies over Pd catalysts
Doskočilová, Danica, et al. Macromolecular Chemistry and Physics 195.8 (1994): 2747-2758.
Abstract The oligomerization products of 1-decene catalyzed by AlCl3 were fractionated by vacuum distillation, and the highest fractions were mainly composed of curling edges. The structures of the fractions were characterized by 1H, 13C NMR and Raman spectroscopy. The oligomers mainly contained long branches, and each molecule always had one double bond, among which tri- and tetra-substituted types were dominant. The structures of trans-4-decene are analyzed, and the polymerization and isomerization mechanisms are discussed.
Assuming that the molar Raman intensities of the corresponding C=C stretching bands are not much different, only the cumulative content of all double bonds can be estimated from the band intensities. The -CH=CH- and >C=CH- groups were examined by analyzing the spectra of trans-4-decene and trans-3-methyl-2-pentene mixed with methyl acetate, using the C=O stretching band of methyl acetate at 1740 cm^-1 as an internal standard. The ratio of the molar intensities of the C=C stretching bands of -CH=CH and >C=CH- groups is about 0.95.
Trans-4-decene used for the study of novel ruthenium carbene dimer catalysis
Buchowicz, Włodzimierz, et al. Journal of organometallic chemistry 588.2 (1999): 205-210.
Ru(=CHPh)Cl2(PCy3)2 reacts with two equivalents of CF3CO2Ag (1) to give Ru2(=CHPh) 2(CF 3 CO2)2-(m-CF3CO2)2(PCy3)2(m-H2O) (2) in high yield. The crystal structure of 2 shows that the ruthenium atom is bridged by two trifluoroacetate groups and a water molecule and that the ruthenium coordination is distorted octahedral. Complex 2 is active in the metathesis of olefins such as trans-4-decene.
The glassware used in these experiments was dried at 120°C for several hours and cooled to the reaction temperature under nitrogen. In a typical experiment, trans-4-decene was added to a solution of complex 2 in an appropriate solvent (0.48 ml). The resulting solution was vigorously stirred and the progress of the metathesis reaction was monitored by sampling through a septum at appropriate time intervals. The catalyst in these samples was immediately quenched with excess ethyl vinyl ether.
Trans-4-decene as a supported ruthenium carbene catalyst
Nieczypor, Piotr, et al. Tetrahedron Letters 42.40 (2001): 7103-7105.
The ruthenium carbene complex was permanently fixed on a functionalized polystyrene resin by reaction with supported silver salts of carboxylic acids. The catalyst prepared in this way is active in the self-metathesis of internal olefins as well as in the ring-closing metathesis. It is easily separated from the reaction products, which are almost free of ruthenium contamination and can be recycled. The polymer-supported catalyst is a highly active and widely used metathesis catalyst for the self-decomposition of internal olefins such as trans-4-decene.
The polymer-supported catalyst 4 and trans-4-decene were added in a ratio of 550:1, reacted in CH2Cl2 and reacted at room temperature for 4 hours. A conversion of 39% was obtained.
What is the molecular formula of trans-4-decene?
The molecular formula of trans-4-decene is C10H20.
What is the molecular weight of trans-4-decene?
The molecular weight of trans-4-decene is 140.27 g/mol.
What is the CAS number of trans-4-decene?
The CAS number of trans-4-decene is 19398-89-1.
What is the IUPAC name of trans-4-decene?
The IUPAC name of trans-4-decene is (E)-dec-4-ene.
What is the InChI of trans-4-decene?
The InChI of trans-4-decene is InChI=1S/C10H20/c1-3-5-7-9-10-8-6-4-2/h7,9H,3-6,8,10H2,1-2H3/b9-7+.
What is the InChIKey of trans-4-decene?
The InChIKey of trans-4-decene is SOVOPSCRHKEUNJ-VQHVLOKHSA-N.
What is the canonical SMILES of trans-4-decene?
The canonical SMILES of trans-4-decene is CCCCCC=CCCC.
What is the isomeric SMILES of trans-4-decene?
The isomeric SMILES of trans-4-decene is CCCCC/C=C/CCC.
What is the XLogP3-AA value of trans-4-decene?
The XLogP3-AA value of trans-4-decene is 4.7.
What is the Rotatable Bond Count of trans-4-decene?
The Rotatable Bond Count of trans-4-decene is 6.
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