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Home > Product > Boronic Compounds > Boronic Acids > 4-Iodophenylboronic acid

4-Iodophenylboronic acid

Catalog Number
ACM5122996
Product Name
4-Iodophenylboronic acid
Structure
CAS Number
5122-99-6
Synonyms
4-IODOBENZENEBORONIC ACID;4-IODOPHENYLBORONIC ACID;RARECHEM AH PB 0035;P-IODOPHENYLBORONIC ACID;4-Iodophenylboronic acid,97%;p-IodophenylboromcAcid;4-Iodophenylboronic acid ,98%;4-Iodophenylboronic
Molecular Formula
C6H6BIO2
Molecular Weight
247.83
Purity
97%
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1Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones.

Boeser CL1, Holder JC2, Taylor BL3, Houk KN3, Stoltz BM2, Zare RN1.

Chem Sci. 2015 Mar;6(3):1917-1922.

An asymmetric palladium-catalyzed conjugate addition reaction of arylboronic acids to enone substrates was investigated mechanistically. Desorption electrospray ionization coupled to mass spectrometry was used to identify intermediates of the catalytic cycle and delineate differences in substrate reactivity. Our findings provide evidence for the catalytic cycle proceeding through formation of an arylpalladium(II) cation, subsequent formation of an arylpalladium-enone complex, and, ultimately, formation of the new C-C bond. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA