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Home > Products > Organic Building Blocks > Organic Phosphine Compounds > 1,1′-Bis(dicyclohexylphosphino)ferrocene

Catalog Number
ACM146960909
Product Name
1,1′-Bis(dicyclohexylphosphino)ferrocene
Structure
CAS
146960-90-9
Synonyms
1,1′-Bis(dicyclohexylphosphino)ferrocene; 1,1-Bis(Dicyclohexylphosphino)Ferrocene; 1,1-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE;
IUPAC Name
dicyclohexyl(cyclopentyl)phosphane;iron
Category
Diphenyl phosphine
Molecular Formula
C34H52FeP2
Molecular Weight
578.57
Exact Mass
578.28900
Melting Point
134-136ºC
Appearance
Orange-red powder
SMILES
C1CCC(CC1)P(C2CCCCC2)[C]3[CH][CH][CH][CH]3.C1CCC(CC1)P(C2CCCCC2)[C]3[CH][CH][CH][CH]3.[Fe]
InChI Key
LVWMUECONASIMT-UHFFFAOYSA-N
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1 Organometallic Fe-Fe Interactions: Beyond Common Metal-Metal Bonds and Inverse Mixed-Valent Charge Transfer.

Ringenberg M1, Schwilk M, Wittkamp F, Apfel UP, Kaim W.

Chemistry. 2016 Dec 11. doi: 10.1002/chem.201605527. [Epub ahead of print]

The compounds [Fe(CO)3(dRpf)]n+, n = 0,1,2 and dRpf = 1,1'-bis(dicyclohexylphosphino)ferrocene ([1]n+) or 1,1' bis(diisopropylphosphino)ferrocene ([2]n+), were obtained as two-step reversible redox systems by photolytic and redox reactions. The iron-iron distance decreases from about 4 Å to ca. 3 Å on oxidation, which takes place primarily at the tricarbonyliron moiety. Whereas ferrocene oxidation ... Read More

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Tel:1-201-478-8534
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