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Home > Product > Precious Metal Catalyst > Rhodium series of catalysts > Tris(triphenylphosphine)rhodium(I)chloride

Tris(triphenylphosphine)rhodium(I)chloride

Catalog Number
ACM14694952
Product Name
Tris(triphenylphosphine)rhodium(I)chloride
Structure
CAS Number
14694-95-2
EC Number
238-744-5
MDL Number
MFCD00010016
IUPAC Name
rhodium;triphenylphosphane;chloride
Synonyms
Wilkinson’s catalyst
Molecular Weight
925.21
Exact Mass
924.14800
Molecular Formula
C54H45ClP3Rh
Boiling Point
>170ºC
Flash Point
181.7ºC
Purity
Rh >11.1%
Appearance
dark red powder
SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]
InChIKey
QBERHIJABFXGRZ-UHFFFAOYSA-M
Safty Description
22-24/25-37/39-28A-26-15
Hazard Statements
Xi: Irritant;
WGK Germany
1
Stability
Stable at room temperature in closed containers under normal storage and handling conditions.
Packing Group
I; II; III
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1Polymeric optical sensors for selective and sensitive nitrite detection using cobalt(III) corrole and rhodium(III) porphyrin as ionophores.

Yang S1, Wo Y1, Meyerhoff ME2.

Anal Chim Acta. 2014 Sep 16;843:89-96. doi: 10.1016/j.aca.2014.06.041. Epub 2014 Jun 26.

Cobalt(III) 5,10,15-tris(4-tert-butylphenyl) corrole with a triphenylphosphine axial ligand and rhodium(III) 5,10,15,20-tetra(p-tert-butylphenyl) porphyrin are incorporated into plasticized poly(vinyl chloride) films to fabricate nitrite-selective bulk optodes via absorbance measurements. The resulting films yield sensitive, fast and fully reversible response toward nitrite with significantly enhanced nitrite selectivity over other anions including lipophilic anions such as thiocyanate and perchlorate. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA