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Catalog Number
ACM5188078
Product Name
Sodium thiomethoxide
Structure
CAS
5188-07-8
Synonyms
SODIUM METHANETHIOLATE;SODIUM METHYL MERCAPTIDE;SODIUM METHYL SULFIDE;SODIUM THIOMETHOXIDE;METHANETHIOL SODIUM SALT;METHYL MERCAPTAN SODIUM SALT;Sodium thiomethoxyde;SODIUM THIOMETHOXIDE, 21 VOL. % SOLN IN WATER, A PRODUCT OF ELF ATOCHEM (SMM)
Molecular Formula
CH3NaS
Molecular Weight
70.09
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1 Total synthesis of serofendic acids A and B employing tin-free homoallyl-homoallyl radical rearrangement.

Toyota M1, Asano T, Ihara M.

Org Lett. 2005 Sep 1;7(18):3929-32.

Total syntheses of serofendic acids A (1a) and B (1b) are described. The key strategic element of the approach involves the novel tin-free homoallyl-homoallyl radical rearrangement of 5 for the construction of bicyclo[2.2.2]octane ring system 4. In addition, the conversion of methyl atisirenoate 2 to serofendic acids A (1a) and B (1b) was achieved on the basis of the Michael reaction of sodium thiomethoxide.[reaction: see text]

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA