Catalog Number
ACM240417009
Category
Organic Phosphine Compounds
Synonyms
SY030636; 2'-(DIPHENYLPHOSPHINO)-N,N-DIMETHYLBIPHENYL-2-AMINE; 2-Dimethylamino-2'-(diphenylphosphino)biphenyl; RL02764; AKOS015840665; 2-(Diphenylphosphino)-2 inverted exclamation mark -(N,N-dimethylamino)biphenyl; 2'-(DIPHENYLPHOSPHINO)-N,N'-DIMETHYL-(1,1'-BIPHENYL)-2-AMINE; 2'-(diphenylphosphanyl)-N,N-dimethyl-[1,1'-biphenyl]-2-amine; 2-DIPHENYLPHOSPHINO-2'-DIMETHYLAMINOBIPHENYL; AN-11455;
IUPAC Name
2-(2-diphenylphosphanylphenyl)-N,N-dimethylaniline;
Molecular Weight
381.459g/mol
Molecular Formula
C26H24NP;
Canonical SMILES
CN(C)C1=CC=CC=C1C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4;
InChI
InChI=1S/C26H24NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h3-20H,1-2H3;
InChI Key
JGFXUYLYPITYGR-UHFFFAOYSA-N;
Application
Useful ligand for sterically hindered substrates in the Pd-catalyzed amination reactions of aryl bromides.
Ligand used for the Cu-catalyzed phosphorylation of alcohols.
Ligand for Pd-catalyzed C-H benzylation.
Ligand for palladium-catalyzed [4 + 2] benzannulation reaction.
Covalently-Bonded Unit Count
1
Monoisotopic Mass
381.165g/mol
Topological Polar Surface Area
3.2A^2
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