Catalog Number
ACM224311493
Category
Organic Phosphine Compounds
Synonyms
2 inverted exclamation marka-(Di-tert-butylphosphino)-N,N-dimethylbiphenyl-2-amine; SCHEMBL238097; t-BuDavePhos, 97%; 2-di(tert-butyl)phosphino-2'-(N,N-dimethylamino)biphenyl; AB0005790; J3.548.578C; MFCD03426986; tBuDavePhos; [2'-(DI-TERT-BUTYL-PHOSPHANYL)-BIPHENYL-2-YL]-DIMETHYL-AMINE; SC-73179;
IUPAC Name
2-(2-ditert-butylphosphanylphenyl)-N,N-dimethylaniline;
Molecular Weight
341.479g/mol
Molecular Formula
C22H32NP;
Canonical SMILES
CC(C)(C)P(C1=CC=CC=C1C2=CC=CC=C2N(C)C)C(C)(C)C;
InChI
InChI=1S/C22H32NP/c1-21(2,3)24(22(4,5)6)20-16-12-10-14-18(20)17-13-9-11-15-19(17)23(7)8/h9-16H,1-8H3;
InChI Key
PHLPNEHPCYZBNZ-UHFFFAOYSA-N;
Application
Useful ligand for Pd-catalyzed carbon-oxygen bond forming reactions.
Ligand used selective Pd-catalyzed arylation of ammonia. Application to the synthesis of dibenzodiazepines.
Ligand used for selective Pd-catalyzed silylation of aryl chlorides.
Ligand used for Pd(0)-catalyzed direct dehydrative coupling of terminal alkynes with allylic alcohols to access 1,4-enynes.
Covalently-Bonded Unit Count
1
Monoisotopic Mass
341.227g/mol
Topological Polar Surface Area
3.2A^2