[NH2Me2][(RuCl((R)-binap))2(μ-Cl)3]

• CAS: 199684-47-4
• Catalog Number: ACM199684474
• Category: Ruthenium series catalysts
• Molecular Weight: 1673.882g/mol
• Molecular Formula: C90H75Cl5NP4Ru2+
• Synonyms: J-012887; (R)-[(RuCl(BINAP))2( -Cl)3][NH2Me2]; DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II); 199684-47-4; 199541-17-8; Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]diruthenate(II), [NH2Me2][{RuCl((R)-binap)}2(mu-Cl)3]; (R)-[(RuCl(BINAP))2(mu-Cl)3[NH2Me2]; DIMETHYLAMMONIUM DICHLOROTRI(MU-CHLORO)BIS[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]DIRUTHENATE(II); (R)-[(RuCl(BINAP))2(|I-Cl)3[NH2Me2]
• IUPAC Name: [1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;N-methylmethanamine;ruthenium;trichloronioruthenium(1-);chloride;hydrochloride
• Canonical SMILES: CNC.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl.[Cl-].[ClH+][Ru-]([ClH+])[ClH+].[Ru]
• InChI: InChI=1S/2C44H32P2.C2H7N.5ClH.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-32H;3H,1-2H3;5*1H;;/q;;;;;;;;;+2/p-1
• InChI Key: NVDGOPZSESFSJS-UHFFFAOYSA-M
• Application: (R)-BINAP or (R)-Tol-BINAP can be combined with dichloro(1,5-cyclooctadiene)ruthenium to form precursors to NOYORI CATALYST SYSTEMS. These systems exhibit very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates. NOYORI CATALYST SYSTEMS have been shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydroxy, siloxy, carbonyl, ester, amide or thioester.; ; Useful ligand in asymmetric Heck processes.; ; Ligand employed in palladium-catalyzed asymmetric arylation of ketones.; ; Ligand employed in rhodium-catalyzed 1,4-additions to enones.; ; Ligand employed in palladium-catalyzed hydroamination of styrene derivatives.; ; Ligand employed in silver-catalyzed asymmetric Sakuri-Hosomi allylation and Mukaiyama aldol reaction.; ; Ligand employed in rhodium-catalyzed kinetic resolution of enynes.; ; Ligand employed in asymmetric rhodium-catalyzed hydroboration of cyclopropenes.; ; Ligand employed in silver-catalyzed a-hydroxylation of stannyl enol ethers.; ; Ligand employed in palladium-catalyzed synthesis of chiral allenes.; ; Ligand for palladium-catalyzed enantioselective hetero Michael addition to form b-amino acid derivatives.; ; Ligand employed in rhodium-catalyzed asymmetric rearrangement of alkynyl alkenyl carbinols.; ; Ligand employed in rhodium-catalyzed 1,2-addition of aluminium organyl compounds to cyclic enones.; ; Ligand employed in iridium-catalyzed transfer hydrogenative allylation of benzylic alcohols.; ; Ligand employed in rhodium-catalyzed asymmetric C-Si bond formation by conjugate silyl transfer using a Si-B linkage.
• Storage: 2-8°C
• Complexity: 809
• Covalently-Bonded Unit Count: 7
• Exact Mass: 1676.136g/mol
• Formal Charge: 1
• H-Bond Acceptor: 3
• H-Bond Donor: 5
• Heavy Atom Count: 102
• Monoisotopic Mass: 1672.138g/mol
• Rotatable Bond Count: 14
• Topological Polar Surface Area: 12A^2