Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II), min. 90%

• CAS: 212143-23-2
• Catalog Number: ACM212143232
• Category: Ruthenium series catalysts
• Molecular Weight: 1006.954g/mol
• Molecular Formula: C58H48Cl2N2P2Ru
• Synonyms: 735D877; Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine] ruthenium(II), 95%; SC10163; C58H48Cl2N2P2Ru; Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine)ruthenium(II); J-013922; RUCL2((S)-BINAP)(R,R-DPEN); DICHLORO[(R)-(+)-2,2-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II)
• IUPAC Name: dichlororuthenium;(1R,2R)-1,2-diphenylethane-1,2-diamine;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane
• Canonical SMILES: C1=CC=C(C=C1)C(C(C2=CC=CC=C2)N)N.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ru]Cl
• InChI: InChI=1S/C44H32P2.C14H16N2.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h1-32H;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1
• InChI Key: PZTVCDSGEXHVBL-ODQAEMFESA-L
• Application: Sequential asymmetric hydrogenation reactions with solution or polymer-bound BINAP/Diamine complexes.; ; Asymmetic hydrogenation of imines.; ; Catalysts for deracemization of benzylic alcohols.
• Complexity: 971
• Covalently-Bonded Unit Count: 3
• Defined Atom Stereocenter Count: 2
• Exact Mass: 1006.171g/mol
• H-Bond Acceptor: 2
• H-Bond Donor: 2
• Heavy Atom Count: 65
• Monoisotopic Mass: 1006.171g/mol
• Rotatable Bond Count: 10
• Topological Polar Surface Area: 52A^2

Custom Q&A

What is the Molecular formula of Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)?

C58H48Cl2N2P2Ru

What is the Molecular weight of Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)?

1006.9

What is the Melting point of Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)?

351-353℃

What is the Sensitivity of Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)?

Air sensitive, store cold

What is the Form of Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)?

Powder

What is the Storage condition of Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)?

-20°C