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Catalog Number
ACM16872096
Product Name
O-Carborane
Structure
CAS
16872-09-6
Synonyms
1,2-Dicarba-closo-dodecaborane(12);1,2-Dicarbadodecaboran;barene;decarborinene;dekene;o-Baren;o-barene;o-Carbaboran
Molecular Formula
C2H12B10
Molecular Weight
144.23
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1 Photoarylation of Iodocarboranes with Unactivated (Hetero)Arenes: Facile Synthesis of 1,2-[(Hetero)Aryl]n -o-Carboranes (n=1,2) and o-Carborane-Fused Cyclics.

Ni H1, Qiu Z2, Xie Z1,2.

Angew Chem Int Ed Engl. 2016 Dec 19. doi: 10.1002/anie.201610810. [Epub ahead of print]

Photoarylation of iodocarboranes with unactivated arenes/heteroarenes at room temperature has been achieved, for the first time, thus leading to the facile synthesis of a large variety of cage carbon mono(hetero)arylated and di(hetero)arylated o-carboranes. This work represents a clean, efficient, transition-metal-free, and cheap synthesis of functionalized carboranes, which has significant advantages over the known methods.© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA