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Home > Products > Material & Chemicals > Micro/NanoElectronics > Bromopentacarbonylmanganese(I)

Catalog Number
ACM14516542
Product Name
Bromopentacarbonylmanganese(I)
Structure
CAS
14516-54-2
Synonyms
14516-54-2;Bromopentacarbonylmanganese(I);Manganese pentacarbonyl bromide;Bromopentacarbonylmanganese(I) 98%;MFCD00049806;J-008065;
EC Number
238-522-8
IUPAC Name
carbon monoxide;manganese;bromide;
Molecular Formula
C5BrMnO5-;
Molecular Weight
274.892g/mol
Exact Mass
273.831g/mol
Monoisotopic Mass
273.831g/mol
Topological Polar Surface Area
5A^2
Heavy Atom Count
12
Formal Charge
-1
Complexity
10
Covalently-Bonded Unit
7
SMILES
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Mn].[Br-];
InChI
InChI=1S/5CO.BrH.Mn/c5*1-2;;/h;;;;;1H;/p-1;
InChI Key
LOCZKKJCQVRJPQ-UHFFFAOYSA-M;
H-Bond Acceptor
6
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1 A mild synthesis of unsymmetrical bisalkoxysilanes through catalyzed alcoholysis of hydridosilanes containing C-C multiple bonds and aryl halides.

Scott CN1, Wilcox CS.

J Org Chem. 2010 Jan 1;75(1):253-6. doi: 10.1021/jo9022765.

The synthesis of unsymmetrical bisalkoxysilanes containing unsaturated C-C bonds and alkyl and aryl bromides has been developed. This method is a modification of our previously reported two-step procedure that utilizes readily available catalysts (rhodium acetate dimer and manganese pentacarbonyl bromide) under mild neutral aprotic conditions. Good to moderate yields of the products were obtained in a short period. In this two-step synthesis, unsymmetrical bisalkoxysilanes with groups that can be further functionalized can be prepared effectively without the need to isolate the intermediates.

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA