Ochiai T1, Franz D, Irran E, Inoue S.
Chemistry. 2015 Apr 27;21(18):6704-7. doi: 10.1002/chem.201500607. Epub 2015 Mar 12.The novel amino(imino)stannylene 1 was prepared by conversion of HNIPr (NIPr = bis(2,6-diisopropylphenyl)imidazolin-2-imino) with one equivalent of Lappert's tin reagent (Sn[N(SiMe3)2]2). Treatment of 1 with DMAP (4-dimethylaminopyridine) yields its Lewis acid-base adduct 2. The reaction of 1 with one equivalent of trimethylsilyl azide results in replacement of the amino group at the tin center by ... Read More