Hibi D1, Kitabayashi K1, Fujita K1, Takeda T1, Tobe Y1.
J Org Chem. 2016 May 6;81(9):3735-43. doi: 10.1021/acs.joc.6b00389. Epub 2016 Apr 8.Diindenopyrene 4b and its diastereomer, which are extended homologues of 1,6- and 1,8-pyrenoquinodimethanes fused by indene units, respectively, were synthesized by reaction of 1,4,5,8-tetrakis(mesitylethynyl)naphthalene (7) with bis(2,4,6-trimethylpyridine)iodine(I) hexafluorophosphate via cationic cyclization mechanisms at both centers of reaction. Unexpectedly, reaction of 7 with iodine, a reage ... Read More