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Home > Products > Material & Chemicals > Micro/NanoElectronics > 7-tert-Butoxynorbornadiene

Catalog Number
ACM877065
Product Name
7-tert-Butoxynorbornadiene
Structure
CAS
877-06-5
Synonyms
7-NORBORNADIENYL TERT-BUTYL ETHER;7-TERT-BUTOXY-2,5-NORBORNADIENE;7-(TERT-BUTOXY)BICYCLO[2.2.1]HEPTA-2,5-DIENE;7-TERT-BUTOXYNORBORNADIENE;7-Norbornadienyl t-butyl ether;Bicyclo[2.2.1]hepta-2,5-dien-7-yl tert-butyl ether;Bicyclo[2.2.1]hepta-2,5-diene, 7-(1
EC Number
212-885-2
IUPAC Name
7-[(2-methylpropan-2-yl)oxy]bicyclo[2.2.1]hepta-2,5-diene
Molecular Formula
C11H16O
Molecular Weight
164.24
Exact Mass
164.12000
Boiling Point
70-72ºC14 mm Hg(lit.)
Flash Point
127 °F
Density
0.936 g/mL at 25ºC(lit.)
SMILES
CC(C)(C)OC1C2C=CC1C=C2
InChI Key
PTTSCAGWOHYHDN-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
1
Safty Description
S23-S24/25
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1 Total synthesis of punctaporonin C by a regio- and stereoselective [2+2]-photocycloaddition.

Fleck M1, Bach T.

Chemistry. 2010 May 25;16(20):6015-32. doi: 10.1002/chem.201000036.

The unique sesquiterpene punctaporonin C was synthesized starting from commercially available 7-tert-butoxynorbornadiene in a linear sequence of 29 steps and with an overall yield of 0.65%. Key step of the synthesis was an intramolecular [2+2]-photocycloaddition, in which the two vinylic double bonds in a 1,3-divinyl-2-cyclopentyl tetronate were differentiated by reaction with the photoexcited tetr ... Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA