Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(S-DOSP)4

Name: Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) Rh2(S-DOSP)4
SKU: ACM179162346

CAS

179162-34-6

Catalog Number

ACM179162346

Category

Rhodium series of catalysts

Molecular Weight

1900.259g/mol

Molecular Formula

C92H148N4O16Rh2S4;

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Specification

Synonyms

RH2(S-DOSP)4;TETRAKIS[(S)-(-)-N-(P-DODECYLPHENYLSULFONYL)PROLINATO]DIRHODIUM(II);179162-34-6;Tetrakis[1-[[4-alkyl(C11-C13)phenyl]sulfonyl]-(2S)-pyrrolidinecarboxylate]dirhodium(II);MFCD04974246;SC10362;dirhodium(ii) tetrakis[N-[(4-dodecylphenyl)sulfonyl]-(s)-prolinate];Rhodium, tetrakis[m-[1-[(4-dodecylphenyl)sulfonyl]-L-prolinato-kO2:kO2']]di-, (Rh-Rh);Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II), Rh2(S-DOSP)4;

IUPAC Name

(2S)-1-(4-dodecylphenyl)sulfonylpyrrolidine-2-carboxylic acid;rhodium;

Canonical SMILES

CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC2C(=O)O.CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC2C(=O)O.CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC2C(=O)O.CCCCCCCCCCCCC1=CC=C(C=C1)S(=O)(=O)N2CCCC2C(=O)O.[Rh].[Rh];

InChI

InChI=1S/4C23H37NO4S.2Rh/c4*1-2-3-4-5-6-7-8-9-10-11-13-20-15-17-21(18-16-20)29(27,28)24-19-12-14-22(24)23(25)26;;/h4*15-18,22H,2-14,19H2,1H3,(H,25,26);;/t4*22-;;/m0000../s1;

InChI Key

IGTBJBHOQXYDMM-JOECBHQBSA-N;

Complexity

1240

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Exact Mass

1898.788g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

118

Monoisotopic Mass

1898.788g/mol

Rotatable Bond Count

Topological Polar Surface Area

332A^2

January 20, 2023

Work good in asymmetric synthesis
Tetrakis[(S)-(-)-N-(p-dodecylphenylsulfonyl)prolinato]dirhodium(II) is used as asymmetric catalyst for asymmetric cyclopropanation /Cope rearrangement in series.