(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 95%

• CAS: 71423-54-6
• Catalog Number: ACM71423546
• Category: Rhodium series of catalysts
• Molecular Weight: 756.371g/mol
• Molecular Formula: C36H40BF4O2P2Rh-
• Synonyms: 71423-54-6;MFCD01074456;(S,S)-(+)-1,2-BIS[(O-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;RH-(S,S)-DIPAMP;SC10327;(1Z,5Z)-cycloocta-1,5-diene,(S)-(2-methoxyphenyl)-[2-[(2-methoxyphenyl)-phenylphosphanyl]ethyl]-phenylphosphane,rhodium,tetrafluoroborate;[((S,S)-1,2-BIS[(2-METHOXYPHENYL)(PHENYL)PHOSPHINO]ETHANE)(1,5-CYCLOOCTADIENE)RHODIUM(I)] TETRAFLUOROBORATE;[[(S,S)-1,2-ETHANEDIYL-BIS-[(2-METHOXYPHENYL)-PHENYLPHOSPHINE]]-(1,5-CYCLOOCTADIENE)-RHODIUM(I)]-TETRAFLUOROBORATE
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;(S)-(2-methoxyphenyl)-[2-[(2-methoxyphenyl)-phenylphosphanyl]ethyl]-phenylphosphane;rhodium;tetrafluoroborate
• SMILES: [B-](F)(F)(F)F.COC1=CC=CC=C1P(CCP(C2=CC=CC=C2)C3=CC=CC=C3OC)C4=CC=CC=C4.C1CC=CCCC=C1.[Rh]
• InChI: InChI=1S/C28H28O2P2.C8H12.BF4.Rh/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h3-20H,21-22H2,1-2H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t31-,32-;;;/m0.../s1
• InChI Key: DCGUTTVLWMBBAX-MPKHXIGSSA-N
• Application: Highly reactive enantioselective catalyst for the asymmetric hydrogenation of various substituted dehydroalanines to Nprotected aminoacids. Also, catalyst is very effective in the asymmetric reduction of pentapetides that contain unsaturated Phe or Tyr linkages to enkephalin, a brain peptide hormone.; ; Efficient catalyst for the asymmetric reduction of enol acetates to esters.; ; Catalyst used to prepare chiral 2-substituted succinic acid derivatives.
• Complexity: 563
• Covalently-Bonded Unit Count: 4
• Defined Atom Stereocenter Count: 2
• Defined Bond Stereocenter Count: 2
• Exact Mass: 756.159g/mol
• Formal Charge: -1
• H-Bond Acceptor: 7
• Heavy Atom Count: 46
• Monoisotopic Mass: 756.159g/mol
• Rotatable Bond Count: 9
• Topological Polar Surface Area: 18.5A^2

Custom Reviews

January 20, 2023

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Work great in asymmetric catalysis
In asymmetric synthesis, (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate can efficiently catalyze the asymmetric reduction of enol acetate to ester.

Custom Q&A

What is molecular formula of (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

C36H40BF4O2P2Rh

What is the sensitivity of (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

Air sensitive

What is the CAS number of (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

71423-54-6

What is exact mass of (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

756.15877

What is hydrogen bond acceptor count of (S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosph(S,S)-(+)-1,2-Bis[(o-methoxyphenyl)(phenyl)phosphino]ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate?

7