Dichloro[(S)-(-)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II), min. 95%

• CAS: 821793-36-6
• Catalog Number: ACM821793366
• Category: Other Products
• Molecular Weight: 1030.93g/mol
• Molecular Formula: C52H52Cl2N4O4P2Ru
• Synonyms: 821793-36-6;(R)-P-Phos RuCl2 (R,R)-DPEN;(S)-P-Phos RuCl2 (S,S)-DPEN;Dichloro[(R)-4,4'-bis(diphenylphosphino)-2,2',6,6'-tetramethoxy-3,3'-bipyridine][(R,R)-DPEN]ruthenium(II);Dichloro[(S)-4,4'-bis(diphenylphosphino)-2,2',6,6'-tetramethoxy-3,3'-bipyridine][(S,S)-DPEN]ruthenium(II)
• IUPAC Name: (1S,2S)-1,2-diphenylethane-1,2-diamine;[3-(4-diphenylphosphaniumyl-2,6-dimethoxypyridin-3-yl)-2,6-dimethoxypyridin-4-yl]-diphenylphosphanium;ruthenium;dichloride
• SMILES: COC1=NC(=C(C(=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3)C4=C(N=C(C=C4[PH+](C5=CC=CC=C5)C6=CC=CC=C6)OC)OC)OC.C1=CC=C(C=C1)C(C(C2=CC=CC=C2)N)N.[Cl-].[Cl-].[Ru]
• InChI: InChI=1S/C38H34N2O4P2.C14H16N2.2ClH.Ru/c1-41-33-25-31(45(27-17-9-5-10-18-27)28-19-11-6-12-20-28)35(37(39-33)43-3)36-32(26-34(42-2)40-38(36)44-4)46(29-21-13-7-14-22-29)30-23-15-8-16-24-30;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h5-26H,1-4H3;1-10,13-14H,15-16H2;2*1H;/t;13-,14-;;;/m.0.../s1
• InChI Key: ONPAXHVWKWGZOZ-LISIALKWSA-N
• Application: Effective catalyst for the highly enantioselective hydrogenation of a diverse range of simple aromatic ketones.
• Complexity: 949
• Covalently-Bonded Unit Count: 5
• Defined Atom Stereocenter Count: 2
• Exact Mass: 1030.188g/mol
• H-Bond Acceptor: 10
• H-Bond Donor: 2
• Heavy Atom Count: 65
• Monoisotopic Mass: 1030.188g/mol
• Rotatable Bond Count: 11
• Topological Polar Surface Area: 115A^2

Custom Reviews

January 20, 2023

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An effective chiral catalyst
In the catalytic reaction, dichloro[(S)-(-)-2,2',6,6'-tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) is an effective catalyst for the high enantioselectivity hydrogenation of simple aromatic ketones.