Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]

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Catalog Number
ACM325146814
Product Name
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-binap]
Structure
Structure
CAS
325146-81-4
Category
Ruthenium series catalysts
Synonyms
Bis(acetato)(binap) ruthenium; Diacetato[(R)-(+)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl]ruthenium(II); Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), Ru(OAc)2[(R)-binap]; DIACETATO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II); RU(OAC)2[(R)-BINAP]; DIACETATO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II); Diacetato[(S)-(-)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl]ruthenium(II); SC10141; 325146-81-4;
IUPAC Name
acetic acid;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium;
Molecular Weight
843.862g/mol
Molecular Formula
C48H40O4P2Ru;
Canonical SMILES
CC(=O)O.CC(=O)O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Ru];
InChI
InChI=1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);;
InChI Key
XANQJWCSQJDBEA-UHFFFAOYSA-N;
Application
Catalyst system that exhibits very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates.

Catalyst used in the synthesis of β-amino acids by hydrogenation.
Storage
2-8°C
Complexity
875
Covalently-Bonded Unit Count
4
Exact Mass
844.145g/mol
H-Bond Acceptor
4
H-Bond Donor
2
Heavy Atom Count
55
Monoisotopic Mass
844.145g/mol
Rotatable Bond Count
7
Topological Polar Surface Area
74.6A^2
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