D-Isoascorbic Acid

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Catalog Number
ACM89656
Product Name
D-Isoascorbic Acid
Structure
Structure
CAS
89-65-6
Category
Heterocyclic Organic Compound
Description
Erythorbic acid (isoascorbic acid, D-araboascorbic acid) is a stereoisomer of ascorbic acid (vitamin C). It is synthesized by a reaction between methyl 2-keto-D-gluconate and sodium methoxide. It can also be synthesized from sucrose or by strains of Penicillium that have been selected for this feature. It is denoted by E number E315, and is widely used as an Antioxidants in processed foods.Clinical trials have been conducted to investigate aspects of the nutritional value of erythorbic acid.One such trial investigated the effects of erythorbic acid on vitamin C metabolism in young women; no effect on vitamin C uptake or clearance from the body was found. A later study found that erythorbic acid is a potent enhancer of nonheme-iron absorption.Since the U.S. Food and Drug Administration banned the use of sulfites as a preservative in foods intended to be eaten fresh (such as salad bar ingredients), the use of erythorbic acid as a food preservative has increased.It is also used as a preservative in cured meats and frozen vegetables.It was first synthesized in 1933 by the German chemists Kurt Maurer and Bruno Schiedt.
Synonyms
D-Araboascorbic Acid
IUPAC Name
(2R)-2-[(1R)-1,2-dihydroxyethyl]-3,4-dihydroxy-2H-furan-5-one
Molecular Weight
176.12
Molecular Formula
C6H8O6
Canonical SMILES
C([C@H]([C@@H]1C(=C(C(=O)O1)O)O)O)O
InChI
InChI=1S/C6H8O6/c7-1-2(8)5-3(9)4(10)6(11)12-5/h2,5,7-10H,1H2/t2-,5-/m1/s1
InChI Key
CIWBSHSKHKDKBQ-DUZGATOHSA-N
Boiling Point
502.7 °C at 760 mmHg
Melting Point
167-172 ºC
Flash Point
238.2±23.6 °C
Density
2.0±0.1 g/cm3
Appearance
Crystals
EC Number
201-928-0
Exact Mass
176.03200
Hazard Codes
Xi
Hazard Statements
Xi: Irritant;
H-Bond Acceptor
6
H-Bond Donor
4
HS Code
2932209090
LogP
-1.40740
PSA
17.22
Refractive Index
1.711
Safety Description
S24/25
Stability
Stable. Combustible. Incompatible with chemically active metals, aluminium, zinc, copper, magnesium, strong bases, strong oxidizing agents.
Storage Conditions
Store at 0-5ºC
WGK Germany
2
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