Chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II) tetrafluoroborate, min. 97%

• CAS: 1150112-54-1
• Catalog Number: ACM1150112541
• Category: Ruthenium series catalysts
• Molecular Weight: 1227.47g/mol
• Molecular Formula: C70H56BClF4NP3Ru
• Synonyms: MFCD17018819;SC10316;1150112-54-1;1150316-02-1;CHLORO[(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-2-(DIPHENYLPHOSPHINO)-1,2-DIPHENYLETHANAMINE]RUTHENIUM(II) TETRAFLUOROBORATE;CHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-2-(DIPHENYLPHOSPHINO)-1,2-DIPHENYLETHANAMINE]RUTHENIUM(II) TETRAFLUOROBORATE;Cl[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]Ru(II) BF4
• IUPAC Name: (1R,2R)-2-diphenylphosphanyl-1,2-diphenylethanamine;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium(2+);chloride;tetrafluoroborate
• InChI: InChI=1S/C44H32P2.C26H24NP.BF4.ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;27-25(21-13-5-1-6-14-21)26(22-15-7-2-8-16-22)28(23-17-9-3-10-18-23)24-19-11-4-12-20-24;2-1(3,4)5;;/h1-32H;1-20,25-26H,27H2;;1H;/q;;-1;;+2/p-1/t;25-,26-;;;/m.1.../s1
• InChI Key: XCERQXGLTGTHLA-CVWRRACQSA-M
• Complexity: 1230
• Covalently-Bonded Unit Count: 5
• Defined Atom Stereocenter Count: 2
• Exact Mass: 1227.239g/mol
• H-Bond Acceptor: 7
• H-Bond Donor: 1
• Heavy Atom Count: 81
• Monoisotopic Mass: 1227.239g/mol
• Rotatable Bond Count: 13
• Topological Polar Surface Area: 26A^2

Custom Reviews

January 20, 2023

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High-efficiency hydrogenation catalyst
Using alcohol as solvent, chloro[(R)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(1R,2R)-2-(diphenylphosphino)-1,2-diphenylethanamine]ruthenium(II) tetrafluoroborate and hydrogen donor catalyze the reduction and hydrogenation of allyl alcohol.