(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97% (S,S)-NORPHOS-Rh

• CAS: 78355-59-6
• Catalog Number: ACM78355596
• Category: Other Products
• Molecular Weight: 760.406g/mol
• Molecular Formula: C39H40BF4P2Rh-
• Synonyms: MFCD09839138;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(2S,3S)-(+)-2,3-Bis(diphenylphosphino)bicyclo[2.2.1]hept-5-ene(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.97%(S,S)-NORPHOS-Rh;78355-59-6
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;[(1R,2S,3S,4S)-3-diphenylphosphanyl-2-bicyclo[2.2.1]hept-5-enyl]-diphenylphosphane;rhodium;tetrafluoroborate
• Canonical SMILES: [B-](F)(F)(F)F.C1CC=CCCC=C1.C1C2C=CC1C(C2P(C3=CC=CC=C3)C4=CC=CC=C4)P(C5=CC=CC=C5)C6=CC=CC=C6.[Rh]
• InChI: InChI=1S/C31H28P2.C8H12.BF4.Rh/c1-5-13-26(14-6-1)32(27-15-7-2-8-16-27)30-24-21-22-25(23-24)31(30)33(28-17-9-3-10-18-28)29-19-11-4-12-20-29;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h1-22,24-25,30-31H,23H2;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t24-,25+,30-,31-;;;/m0.../s1
• InChI Key: DPXNIIPVFLWYAU-KCRFXNLBSA-N
• Application: Ligand used in the enantioselective rhodium catalyzed hydrogenation of α-dehydroaminoesters and enamides.; ; Ligand used in the enantioselective rhodium catalyzed hydroboration of cyclopropenes.; ; Ligand used in the asymmetric rhodium catalyzed cleavage of racemic 1,3-oxazolidines.
• Complexity: 635
• Covalently-Bonded Unit Count: 4
• Defined Atom Stereocenter Count: 4
• Defined Bond Stereocenter Count: 2
• Exact Mass: 760.169g/mol
• Formal Charge: -1
• H-Bond Acceptor: 5
• Heavy Atom Count: 47
• Monoisotopic Mass: 760.169g/mol
• Rotatable Bond Count: 6
• Topological Polar Surface Area: 0A^2

Custom Reviews

December 15, 2022

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Works great!
Our lab uses the reagent and found it works fine.