(1S)-(+)-Camphor-10-sulfonic acid(dry wt.),water

• CAS: 3144-16-9
• Catalog Number: ACM3144169
• Category: Other Products
• Molecular Weight: 232.294g/mol
• Molecular Formula: C10H16O4S
• Synonyms: (1S)-(+)-10-Camphorsulfonic acid, 99%; Camphersulfosaeure [German]; ST2408078; DL-10-Camphorsulfonic acid; CS-D1796; [(1S,4R)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptan-1-yl]methanesulfonic acid; Voriconazole Impurity E; D-Camphor sulfonic acid, United States Pharmacopeia (USP) Reference Standard; MFCD00074827; Camphor-10-sulfonic acid (beta), 98%
• IUPAC Name: [(1S,4R)-7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl]methanesulfonic acid
• SMILES: CC1(C2CCC1(C(=O)C2)CS(=O)(=O)O)C
• InChI: InChI=1S/C10H16O4S/c1-9(2)7-3-4-10(9,8(11)5-7)6-15(12,13)14/h7H,3-6H2,1-2H3,(H,12,13,14)/t7-,10-/m1/s1
• InChI Key: MIOPJNTWMNEORI-GMSGAONNSA-N
• Application: Used as a resolving agent, and as a catalyst for coupling dipeptides.
• Storage: 2-8°C
• Complexity: 404
• Covalently-Bonded Unit Count: 1
• Defined Atom Stereocenter Count: 2
• EC Number: 221-554-1
• Exact Mass: 232.077g/mol
• H-Bond Acceptor: 4
• H-Bond Donor: 1
• Heavy Atom Count: 15
• Monoisotopic Mass: 232.077g/mol
• NSC Number: 4167
• Rotatable Bond Count: 2
• Topological Polar Surface Area: 79.8A^2
• UNII: 9TLZ01S15L

Synthetic Use

Upstream Synthesis Route 1

• 357-57-3
• 5872-08-2

• 3144-16-9
• 35963-20-3

Reference: [1]Read; Reid
[Journal of the Society of Chemical Industry, 1928, vol. 47, p. 11 T][Chemisches Zentralblatt, 1928, vol. 99, # I, p. 2374]
Burgess; Gibson
[Journal of the Society of Chemical Industry, 1925, vol. 44, # 497, p. 498 T][Chemisches Zentralblatt, 1926, vol. 97, # I, p. 914]

Downstream Synthesis Route 1

• 866783-12-2
• 3144-16-9
• 155974-00-8

• 1031767-75-5
• 148849-67-6

Reference: [1] Patent: WO2016/193386, 2016, A2, . Location in patent: Page/Page column 16; 17

Downstream Synthesis Route 2

• 3144-16-9

• 60886-80-8

Reference: [1] Organic Letters, 2018, vol. 20, # 11, p. 3286 - 3290

Downstream Synthesis Route 3

• 3144-16-9

• 60886-80-8

Reference: [1]Organic Letters,2018,vol. 20,p. 3286 - 3290

* For details of the synthesis route, please refer to the original source to ensure accuracy.