(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 98% (R,R)-i-Pr-DUPHOS-Rh

• CAS: 569650-64-2
• Catalog Number: ACM569650642
• Category: Other Products
• Molecular Weight: 716.479g/mol
• Molecular Formula: C34H56BF4P2Rh-
• Synonyms: 569650-64-2;1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(R,R)-i-Pr-DUPHOS-Rh;DTXSID00514132;PUBCHEM_12964416;MFCD07369039;(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;(+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(i)tetrafluoroborate
• IUPAC Name: (1Z,5Z)-cycloocta-1,5-diene;(2R,5R)-1-[2-[(2R,5R)-2,5-di(propan-2-yl)phospholan-1-yl]phenyl]-2,5-di(propan-2-yl)phospholane;rhodium;tetrafluoroborate
• InChI: InChI=1S/C26H44P2.C8H12.BF4.Rh/c1-17(2)21-13-14-22(18(3)4)27(21)25-11-9-10-12-26(25)28-23(19(5)6)15-16-24(28)20(7)8;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-12,17-24H,13-16H2,1-8H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t21-,22-,23-,24-;;;/m1.../s1
• InChI Key: IJKOQQHIAGRJHA-QPZXYOTCSA-N
• Application: The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.; ; Forms superior catalysts for asymmetric reductive aminations.; ; Catalyst used for the asymmetric hydrogenation of enol phosphonates.; ; A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.; ; Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.; ; Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.; ; Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.; ; Palladium catalyzed asymmetric phosphination.
• Complexity: 499
• Covalently-Bonded Unit Count: 4
• Defined Atom Stereocenter Count: 4
• Defined Bond Stereocenter Count: 2
• Exact Mass: 716.294g/mol
• Formal Charge: -1
• H-Bond Acceptor: 5
• Heavy Atom Count: 42
• Monoisotopic Mass: 716.294g/mol
• Rotatable Bond Count: 6
• Topological Polar Surface Area: 0A^2

Custom Reviews

December 15, 2022

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good product!
We received and used the product. It works great!