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Catalog Number
ACM131211273
Product Name
Di-1-adamantylphosphine
Structure
CAS
131211-27-3
Synonyms
diadamantyl phosphine; AJ-118442; Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine; SCHEMBL451941; Di-1-adamantylphosphine, 97%; D4781; ST24046438; CS-W008548; Phosphine, bis(tricyclo[3.3.1.13,7]dec-1-yl)-; CTK0H0086;
IUPAC Name
bis(1-adamantyl)phosphane;
Molecular Formula
C20H31P;
Molecular Weight
302.442g/mol
Rotatable Bond Count
2
Exact Mass
302.216g/mol
Monoisotopic Mass
302.216g/mol
Topological Polar Surface Area
0A^2
Heavy Atom Count
21
Complexity
340
Covalently-Bonded Unit
1
SMILES
C1C2CC3CC1CC(C2)(C3)PC45CC6CC(C4)CC(C6)C5;
InChI
InChI=1S/C20H31P/c1-13-2-15-3-14(1)8-19(7-13,9-15)21-20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18,21H,1-12H2;
InChI Key
RRRZOLBZYZWQBZ-UHFFFAOYSA-N;
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1 Two methods for direct ortho-arylation of benzoic acids.

Chiong HA1, Pham QN, Daugulis O.

J Am Chem Soc. 2007 Aug 15;129(32):9879-84. Epub 2007 Jul 25.

Two new palladium-catalyzed methods for the direct ortho-arylation of free benzoic acids have been developed. The first method employs stoichiometric silver acetate for iodide removal, aryl iodide as the coupling partner, and acetic acid solvent. This method is applicable to the arylation of electron-rich to moderately electron-poor benzoic acids and tolerates chloride and bromide substituents on b ... Read More

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA