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Heat-resistant network block copolymers based on rolivsans modified with tetracarboxylic anhydrides and aromatic tetraamines

Zaitsev B A, Shvabskaya I D, Kleptsova L G

Russian Journal of Applied Chemistry, 2018, 91(6): 1029-1034

The efficiency of a new approach to structural-chemical modification of unsaturated thermosetting resins was demonstrated by the example of curing of rolivsans containing small additions (0.5–2.0 wt %) of aromatic tetracarboxylic dianhydrides and aromatic tetraamines. As shown by dynamic mechanical and thermal analysis, the heat resistance of the modified matrix of the cured rolivsan, which is mainly used as a heat-resistant polymer compound for electric insulation, increases from 280 to 340–375°С, and the rigidity parameters decrease by a factor of 3–6, which is of much practical interest.

Chemicals Related in the Paper:

Catalog Number Product Name Structure CAS Number Price
ACM2676597 3,3',4,4'-Tetraaminodiphenyl ether 3,3',4,4'-Tetraaminodiphenyl ether 2676-59-7 Price

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