CONTACT US

Email: info@alfa-chemistry.com
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA

For product inquiries, please use our online system or send an email to
inquiry@alfa-chemistry.com

chemistry partner
Home > Products > Organic Building Blocks > Alkenes > Allyloxytrimethylsilane

Catalog Number
ACM18146004
Product Name
Allyloxytrimethylsilane
Structure
CAS
18146-00-4
Symbol
GHS02
Synonyms
Allyl trimethylsilyl ether; Allyloxytrimethylsilane; trimethylallyloxysilane; AllyloxytriMethylsilane; O-(trimethylsilyl)allyl alcohol; 3-trimethylsiloxy-1-propene; 3-(Trimethylsiloxy)propene; Trimethyl(2-propenyloxy)silane; (2-propenyloxy)trimethylsilane;
EC Number
242-031-4
IUPAC Name
trimethyl(prop-2-enoxy)silane
Category
Organic Building Blocks
Molecular Formula
C7H5ClO
Molecular Weight
130.26
Exact Mass
130.08100
Boiling Point
100-102ºC(lit.)
Flash Point
31 °F
Density
0.773 g/mL at 25ºC(lit.)
Appearance
Transparent liquid
SMILES
C[Si](C)(C)OCC=C
InChI Key
MNMVKGDEKPPREK-UHFFFAOYSA-N
Safty Description
16-26-36
Hazard Statements
H226-H319
WGK Germany
3
Packing Group
II
RIDADR
UN 1993C 3 / PGIII
If you have any other questions or need other size, please get a quote.
  • CAS
  • Size
  • Purity
  • Price
  • Availability
  • Quantity
  • Order
1 Electrochemical selenium- and iodonium-initiated cyclisation of hydroxy-functionalised 1,4-dienes.

Röse P1, Emge S1, Yoshida J2, Hilt G1.

Beilstein J Org Chem. 2015 Jan 28;11:174-83. doi: 10.3762/bjoc.11.18. eCollection 2015.

The cobalt(I)-catalysed 1,4-hydrovinylation reaction of allyloxytrimethylsilane and allyl alcohol with substituted 1,3-dienes leads to hydroxy-functionalised 1,4-dienes in excellent regio- and diastereoselective fashion. Those 1,4-dienols can be converted into tetrahydrofuran and pyran derivatives under indirect electrochemical conditions generating selenium or iodonium cations. The reactions proceed in good yields and regioselectivities for the formation of single diastereomers.

Share

Interested in our Services & Products ? Need detailed information?
facebook twitter linkedin

Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA