Wang H1, Ou J2, Bai J3, Liu Z4, Yao Y4, Chen L4, Peng X5, Zou H6.
J Chromatogr A. 2016 Mar 4;1436:100-8. doi: 10.1016/j.chroma.2016.01.063. Epub 2016 Jan 30.A simple approach was developed for rapid preparation of polymeric monolithic columns in UV-transparent fused-silica capillaries via photoinitiated thiol-acrylate polymerization of pentaerythritol diacrylate monostearate (PEDAS) and trimethylolpropane tris(3-mercaptopropionate) (TPTM) within 10min, in which the acrylate homopolymerized and copolymerized with the thiol simultaneously. The morphology, permeability and chromatographic performance of the resulting poly(PEDAS-co-TPTM) monoliths were studied. Read More