2-(Nonafluorobutyl)ethyl methacrylate

• Catalog Number: ACM1799844-2
• Product Name: 2-(Nonafluorobutyl)ethyl methacrylate
• CAS: 1799-84-4
• Category: Heterocyclic Organic Compound
• Description: 3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate (NFHMA) is a non-toxic, fluorinated monomer that has gained popularity in recent years due to its unique and versatile properties. NFHMA has been used in a variety of applications, ranging from medical to industrial, due to its high thermal stability, low volatility, and excellent solubility. Additionally, NFHMA has been found to be non-toxic and biocompatible, making it an ideal candidate for use in biomedical applications.
• Synonyms: 2-(Perfluorobutyl)ethyl methacrylate
• IUPAC Name: 3,3,4,4,5,5,6,6,6-nonafluorohexyl 2-methylprop-2-enoate
• Molecular Weight: 332.16
• Molecular Formula: C10H9F9O2
• Canonical SMILES: CC(=C)C(=O)OCCC(C(C(C(F)(F)F)(F)F)(F)F)(F)F
• InChI: InChI=1S/C10H9F9O2/c1-5(2)6(20)21-4-3-7(11,12)8(13,14)9(15,16)10(17,18)19/h1,3-4H2,2H3
• InChI Key: TYNRPOFACABVSI-UHFFFAOYSA-N
• Boiling Point: 60-62° C at 5 mmHg
• Flash Point: 79 °C
• Density: 1.402 g/mL
• Appearance: Liquid
• Application: 3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate has been used in a variety of scientific research applications, including drug delivery, tissue engineering, and nanotechnology. In drug delivery, 3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate has been used to create nanocarriers for the delivery of drugs to target sites in the body. In tissue engineering, 3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate has been used to create scaffolds for the growth of new tissues and organs. In nanotechnology, 3,3,4,4,5,5,6,6,6-Nonafluorohexyl methacrylate has been used to create nanostructures for a variety of applications, including sensing, drug delivery, and imaging.
• Storage: Store at -20 ℃
• Complexity: 411
• Covalently-Bonded Unit Count: 1
• EC Number: 217-287-5
• Exact Mass: 332.046
• Formal Charge: 0
• Hazard Codes: F: Flammable;Xi: Irritant
• H-Bond Acceptor: 11
• H-Bond Donor: 0
• Heavy Atom Count: 21
• HTS Code: 2916140000
• MDL Number: MFCD00236094
• Monoisotopic Mass: 332.045883 g/mol
• PSA: 26.3
• Refractive Index: 1.353
• Rotatable Bond Count: 7
• Vapor Pressure: 0.681 mmHg at 25°C
• XLogP3: 4.6

Case Study

RAFT Dispersion Polymerization of 2-(Nonafluorobutyl)ethyl Methacrylate in Ethanol

Huo M, et al. Macromolecular Rapid Communications, 2018, 39(7): 1700840.

Alcoholic reversible addition-fragmentation chain-transfer (RAFT) dispersion polymerization of 2-(perfluorobutyl)ethyl methacrylate (FBEMA) extends the general availability of semifluorinated methacrylates to polymerization-induced self-assembly (PISA).
· The monomer conversion reaches 90% within 11 h, while the corresponding semi-logarithmic plot shows two distinct regimes: the rate of polymerization is relatively slow for the first 3 h, while a dramatic increase in the rate is observed in the following 8 h (Figure 1a).
· Both the two regimes of the curve represent pseudo-first kinetics, suggesting good control of the RAFT polymerization.
· Mn of these block copolymers increases with the monomer conversion, and the dispersities are <1.30 for all the copolymers (Figure 1c).