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Butyl vinyl ether | CAS Number: 111-34-2

Catalog Number
ACM111342
Product Name
Butyl vinyl ether
Structure
CAS Number
111-34-2
EC Number
203-860-7
UN Number
2352
IUPAC Name
1-ethenoxybutane
Synonyms
(BUTYLOXY)ETHYLENE;BUTYL VINYL ETHER;1-(ETHENYLOXY)BUTANE;N-BUTYL VINYL ETHER;VINYL BUTYL ETHER;VINYL N-BUTYL ETHER;1-(ethenyloxy)-butan;1-(Vinyloxy)-butane
Molecular Weight
100.16
Exact Mass
100.08900
Molecular Formula
C6H12O
Boiling Point
94ºC
Melting Point
-92ºC
Flash Point
-9ºC
Density
0.78 (20°C)
Purity
Purity >98%
Appearance
Liquid
SMILES
CCCCOC=C
InChIKey
UZKWTJUDCOPSNM-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
1
Safty Description
S16-S33-S9
Hazard Statements
F:Flammable
WGK Germany
2
Stability
May form explosive peroxides.
Packing Group
II
Alpha Sort
Butyl vinyl ether
Refractive Index
1.4010 (20)
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1Direct generation of oxygen-stabilized radicals by H• transfer from transition metal hydrides.

Kuo JL1, Hartung J, Han A, Norton JR.

J Am Chem Soc. 2015 Jan 28;137(3):1036-9. doi: 10.1021/ja511883b. Epub 2015 Jan 15.

Transition-metal hydrides generate α-alkoxy radicals by H• transfer to enol ethers. We have measured the rate constant for transfer from CpCr(CO)3H to n-butyl vinyl ether and have examined the chemistry of radicals generated by such transfers. Radicals from appropriate substrates undergo 5-exo cyclization, with higher diastereoselectivity than the analogous all-carbon radicals. From such radicals it is straightforward to make substituted tetrahydrofurans.

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA