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Home > Product > Material & Chemicals > Polymer/Macromolecule > 3-(Trifluoromethyl)styrene

3-(Trifluoromethyl)styrene | CAS Number: 402-24-4

Catalog Number
ACM402244
Product Name
3-(Trifluoromethyl)styrene
Structure
CAS Number
402-24-4
Synonyms
Benzene, 1-(trifluoromethyl)-3-(ethenyl)-;3-(TRIFLUOROMETHYL)STYRENE;3-(Trifluoromethyl)styrene, stabilized;3-(TRIFLUOROMETHYL)STYRENE, 98% MIN.;M-TRIFLUOROMETHYLSTYRENE;3-(Trifluoromethyl)styrene, 97+%, stabilised;3-(Trifluoromethyl)styrene,97+%,stabiliz
Molecular Weight
172.15
Molecular Formula
C9H7F3
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1Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF3 Does What B(C6 F5 )3 Cannot Do!

Yin Q1, Kemper S1, Klare HF2, Oestreich M3.

Chemistry. 2016 Sep 19;22(39):13840-13844. doi: 10.1002/chem.201603466. Epub 2016 Aug 12.

The transition-metal-free hydroboration of various alkenes with pinacolborane (HBpin) initiated by tris[3,5-bis(trifluoromethyl)phenyl]borane (BArF3 ) is reported. The choice of the boron Lewis acid is crucial as the more prominent boron Lewis acid tris(pentafluorophenyl)borane (B(C6 F5 )3 ) is reluctant to react. Unlike B(C6 F5 )3 , BArF3 is found to engage in substituent redistribution with HBpin, resulting in the formation of ArF Bpin and the electron-deficient diboranes [H2 BArF ]2 and [(ArF )(H)B(μ-H)2 BArF2 ]. Read More

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Tel:1-201-478-8534
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