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Home > Product > Material & Chemicals > Organic & Printed Electronics > 2,6-Di-tert-butyl-1,3,5,7-pentamethylpyrromethenedifluoroborate complex

2,6-Di-tert-butyl-1,3,5,7-pentamethylpyrromethenedifluoroborate complex | CAS Number: 137829-79-9

Catalog Number
ACM137829799
Product Name
2,6-Di-tert-butyl-1,3,5,7-pentamethylpyrromethenedifluoroborate complex
Structure
CAS Number
137829-79-9
Synonyms
2,6-DI-TERT-BUTYL-1,3,5,7-PENTAMETHYLPYRROMETHENEDIFLUOROBORATE COMPLEX;2,6-Di-tert-butyl-1,3,5,7,8-pentamethylpyrromethenedifluoroborate complex;Boron,[4-(1,1-dimethylethyl)-2-[1-[4-(1,1-dimethylethyl)-3,5-dimethyl-2H-pyrrol-2-ylidene]ethyl]-3,5-dimethyl
Molecular Weight
374.324
Molecular Formula
C22H33BF2N2
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1Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex.

Lee JY1, Peterson RL, Ohkubo K, Garcia-Bosch I, Himes RA, Woertink J, Moore CD, Solomon EI, Fukuzumi S, Karlin KD.

J Am Chem Soc. 2014 Jul 16;136(28):9925-37. doi: 10.1021/ja503105b. Epub 2014 Jul 8.

To obtain mechanistic insights into the inherent reactivity patterns for copper(I)-O2 adducts, a new cupric-superoxo complex [(DMM-tmpa)Cu(II)(O2(•-))](+) (2) [DMM-tmpa = tris((4-methoxy-3,5-dimethylpyridin-2-yl)methyl)amine] has been synthesized and studied in phenol oxidation-oxygenation reactions. Compound 2 is characterized by UV-vis, resonance Raman, and EPR spectroscopies. Its reactions with a series of para-substituted 2,6-di-tert-butylphenols (p-X-DTBPs) afford 2,6-di-tert-butyl-1,4-benzoquinone (DTBQ) in up to 50% yields. Read More

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