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Home > Products > Material & Chemicals > Micro/NanoElectronics > [Tris(dimethylphenylphosphine)](2,5-norbornadiene)rhodium(I) hexafluorophosphate

Catalog Number
ACM32761505
Product Name
[Tris(dimethylphenylphosphine)](2,5-norbornadiene)rhodium(I) hexafluorophosphate
Structure
CAS
32761-50-5
Synonyms
DTXSID80583563; [(2,3-|C)-Bicyclo[2.2.1]hepta-2,5-diene]tris(dimethylphenylphosphine)rhodium(I) hexafluorophosphate; [Tris(dimethylphenylphosphine)](2,5-norbornadiene)rhodium(i)hexafluorophosphate; Tris(dimethylphenylphosphine)](2,5-norbornadiene)rhodium(I) hexafluorophosphate; [(2,3-ETA)-BICYCLO[2.2.1]HEPTA-2,5-DIENE]TRIS(DIMETHYLPHENYLPHOSPHINE)RHODIUM(I) HEXAFLUOROPHOSPHATE;
IUPAC Name
bicyclo[2.2.1]hepta-2,5-diene;dimethyl(phenyl)phosphane;rhodium;hexafluorophosphate;
Molecular Formula
C31H41F6P4Rh-;
Molecular Weight
754.46g/mol
Rotatable Bond Count
3
Exact Mass
754.112g/mol
Monoisotopic Mass
754.112g/mol
Topological Polar Surface Area
0A^2
Heavy Atom Count
42
Formal Charge
-1
Complexity
238
Covalently-Bonded Unit
6
SMILES
CP(C)C1=CC=CC=C1.CP(C)C1=CC=CC=C1.CP(C)C1=CC=CC=C1.C1C2C=CC1C=C2.F[P-](F)(F)(F)(F)F.[Rh];
InChI
InChI=1S/3C8H11P.C7H8.F6P.Rh/c3*1-9(2)8-6-4-3-5-7-8;1-2-7-4-3-6(1)5-7;1-7(2,3,4,5)6;/h3*3-7H,1-2H3;1-4,6-7H,5H2;;/q;;;;-1;;
InChI Key
VMMJZDCWYNRZKV-UHFFFAOYSA-N;
H-Bond Acceptor
7
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1 Solid-state phosphorus-31 NMR spectroscopy of a multiple-spin system: an investigation of a rhodium-triphosphine complex.

Bernard GM1, Feindel KW, Wasylishen RE, Cameron TS.

Phys Chem Chem Phys. 2008 Sep 28;10(36):5552-63. doi: 10.1039/b803596b. Epub 2008 Jul 21.

Phosphorus-31 NMR spectra of solid [tris(dimethylphenylphosphine)](2,5-norbornadiene) rhodium(I) hexafluorophosphate have been acquired at several applied magnetic field strengths. The phosphorus nuclei of the three phosphine ligands are spin-spin coupled to each other and to 103Rh, resulting in complex NMR spectra; however, the three phosphorus chemical shift (CS) tensors were determined through t ... Read More

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Tel:1-201-478-8534
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