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Trioctylsilane

Catalog Number
ACM18765098
Product Name
Trioctylsilane
Structure
CAS Number
18765-09-8
EC Number
242-559-5
IUPAC Name
trioctylsilicon
Synonyms
Trioctylsilane, Silane, trioctyl-, MolPort-003-933-194, NSC139862, EINECS 242-559-5, CID6327367, NSC 139862, 18765-09-8
Category
Organic hydrogen silane
Molecular Weight
368.76
Exact Mass
368.38400
Molecular Formula
C24H52Si
Boiling Point
163-165ºC0.15 mm Hg(lit.)
Flash Point
189.4ºC
Purity
95%
Appearance
Colorless liquid
SMILES
CCCCCCCC[Si](CCCCCCCC)CCCCCCCC
InChIKey
QTKHQYWRGFZFHG-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
Safty Description
26-36
Hazard Statements
Xi: Irritant;
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1Rhodium-catalyzed synthesis of diaryl sulfides using aryl fluorides and sulfur/organopolysulfides.

Arisawa M1, Ichikawa T, Yamaguchi M.

Org Lett. 2012 Oct 19;14(20):5318-21. doi: 10.1021/ol302497m. Epub 2012 Oct 5.

Substituted pentafluorobenzenes react with sulfur to give bis(4-substituted 2,3,5,6-tetrafluorophenyl) sulfides in the presence of RhH(PPh(3))(4), 1,2-bis(diphenylphosphino)benzene (dppBz), and tributylsilane. The reaction proceeds efficiently between room temperature and 80 °C. A comparative study of the reactivities of an organic trisulfide and a tetrasulfide showed notable substrate specificity. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA