CONTACT US

Email: info@alfa-chemistry.com
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA

For product inquiries, please use our online system or send an email to
inquiry@alfa-chemistry.com

chemistry partner
Home > Product > Organic Building Blocks > Alkynes > (Triisopropylsilyl)acetylene

(Triisopropylsilyl)acetylene

Catalog Number
ACM89343066
Product Name
(Triisopropylsilyl)acetylene
Structure
CAS Number
89343-06-6
IUPAC Name
ethynyl-tri(propan-2-yl)silane
Synonyms
(Triisopropylsilyl)acetylene, Ethynyltriisopropylsilane, 89343-06-6, Triisopropylsilylacetylene, AG-H-61586, ethynyl-tri(propan-2-yl)silane, ACMC-209qzk, AC1MC1OT, KSC493G7H, (tri-iso-propylsilyl)acetylene, Ethynyl[tris(isopropyl)]silane, 360031_ALDRICH, Ethynyl[tris(prop-2-yl)]silane, 92097_FLUKA, CTK3J3373, MolPort-000-159-257, ACT10533, ANW-39246, AKOS005257349, OR30591
Category
Organic Building Blocks
Molecular Formula
C11H21F5SSi
Molecular Weight
182.38
Exact Mass
182.14900
Boiling Point
50-52ºC (0.6 mmHg)
Flash Point
56ºC
Density
0.813
Purity
95%+
Appearance
Transparent liquid
SMILES
CC(C)[Si](C#C)(C(C)C)C(C)C
InChIKey
KZGWPHUWNWRTEP-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
Symbol
GHS07
Safty Description
S26-S37/39
Hazard Statements
H315-H319-H335
WGK Germany
3
Packing Group
III
RIDADR
NONH for all modes of transport
If you have any other questions or need other size, please get a quote.
  • CAS
  • Size
  • Purity
  • Price
  • Availability
  • Quantity
  • Order
1Palladium-Catalyzed Alkynylation of Morita-Baylis-Hillman Carbonates with (Triisopropylsilyl)acetylene on Water.

Li Y1, Liu L1, Kong D1, Wang D1, Feng W2, Yue T2, Li C3.

J Org Chem. 2015 Jun 19;80(12):6283-90. doi: 10.1021/acs.joc.5b00728. Epub 2015 Jun 1.

Direct alkynylation of Morita-Baylis-Hillman carbonates with (triisopropylsilyl)acetylene catalyzed by a Pd(OAc)2-NHC complex was developed "on water" to give the corresponding 1,4-enynes. The significant effects of water amount in the solvent on further transformations of 1,4-enynes were investigated.

Share

Interested in our Services & Products ? Need detailed information?
facebook twitter linkedin google+

Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA