Tetramethylammonium chloride

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Catalog Number
ACM75570-3
Product Name
Tetramethylammonium chloride
Structure
Structure
CAS
75-57-0
Category
Ammonium Ionic Liquids
Description
DryPowder; Liquid;HYGROSCOPIC WHITE CRYSTALS.
Synonyms
TMAC
IUPAC Name
tetramethylazanium; chloride
Molecular Weight
109.60
Molecular Formula
C4H12ClN
Canonical SMILES
C[N+](C)(C)C.[Cl-]
InChI
InChI=1S/C4H12N.ClH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1
InChI Key
OKIZCWYLBDKLSU-UHFFFAOYSA-M
Melting Point
420 °C (decomposes)
Density
1.1690 at 20 °C/4 °C;1.17 g/cm³
Solubility
Slightly soluble in ethanol; insoluble in ether, benzene, chloroform; very soluble in methanol;Soluble in alcohol; insoluble in ether;Soluble in water;In water, 5.9X10+5 mg/L at 25 °C (est);Solubility in water at 20 °C: very good
Application
Metal Plating, Electropolishing, Metal Reprocessing, Phase transfer media, Batteries Fuel Cells, Nanomaterials, Industrial Solvents, Nuclear Fuel Red Waste, Enzymatic Catalysis, Lubricants Heat Transfer and Solar Energy Conversion.
Storage
Store at RT.
Chemical Formula
N1,1,1,1Cl
Color/Form
Bipyramidal from dilute alcohol;White crystalline solid
Complexity
19.1
Covalently-Bonded Unit Count
2
Decomposition
When heated to decomposition it emits very toxic fumes of /nitrogen oxides, ammonia and hydrogen chloride/.;368-370 °C
EC Number
200-880-8
Exact Mass
109.066
Formal Charge
0
H-Bond Acceptor
1
H-Bond Donor
0
Heavy Atom Count
6
ICSC Number
1099
LogP
log Kow = -4.18 (est)
MDL Number
MFCD00011628
Monoisotopic Mass
109.066
Octanol Water Partition Coefficient
log Kow = -4.18 (est);
Other Experimental
Hygroscopic;MP: Decomposes;MP: >300 °C;When heated to decomposition it emits very toxic fumes of NOx, NH₃, and Cl(-).;Henry's Law constant = 4.2X10-12 atm-cu m/mol at 25 °C (est);Hydroxyl radical reaction rate constant = 5.1X10-12 cu cm/molec-sec at 25 °C (est)
Physical Description
DryPowder; Liquid;HYGROSCOPIC WHITE CRYSTALS.;
Physical State
White crystals, chunks, or powder
Rotatable Bond Count
0
RTECS Number
BS7700000
Topological Polar Surface Area
0A^2
UNII
DCQ9S88703
UN Number
2811
Vapor Pressure
1.2X10-8 mm Hg at 25 °C (est)
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