Tetradecane

• CAS: 629-59-4
• Catalog Number: ACM629594
• Category: Alkanes
• Molecular Weight: 198.39
• Molecular Formula: C14H30
• Description: N-Tetradecane is one of our strong item to Europe , the quality is highly approved by our customers.
• Synonyms: ALKANE C14;N-TETRADECANE;TETRADECANE OLEFINE FREE;TETRADECANE, N-;TETRADECANE;n-Tetradecan; ;#nn-Tetradecane;N-TETRADECANE OEKANAL
• Boiling Point: 252-254°C(lit.)
• Melting Point: 5.8°C
• Flash Point: 99°C
• Density: 0.767
• Solubility: water, 0.009192 mg/L @ 25 °C (est)
• Appearance: Colorless liquid
• Assay: 0.99
• EC Number: 211-096-0
• Hazard Statements: Xn
• MDL Number: MFCD00008986
• Packaging: 150 kg/DRUMS
• Refractive Index: 1.428-1.43
• RIDADR: NONH for all modes of transport
• Safety Description: 23-24-62-24/25
• Stability: Stable under normal temperatures and pressures.
• Storage Conditions: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
• Supplemental Hazard Statements: H336-H304
• Symbol: GHS08,GHS07

Case Study

Preparation of Nano-Encapsulated n-Tetradecane Phase Change Thermal Storage Materials

Fang, Guiyin, et al. Chemical engineering journal, 2009, 153(1-3), 217-221.

The research demonstrated the creation of nano-encapsulated phase change materials (NEPCM) which utilize n-tetradecane oil as the phase change material (PCM) and urea-formaldehyde resin for the shell component. The nanocapsules can be used for thermal energy storage and enhanced heat transfer.
Preparation procedure of n-tetradecane-based NEPCM
· Urea-formaldehyde prepolymer synthesis: A mixture of 3 g urea, 10 ml H2O, and 14 g formaldehyde solution was prepared in a 100 ml flask. The pH was adjusted to 8-9 using triethanolamine. The mixture was stirred at 200 rpm and 70°C (water bath) for 1 h, yielding a prepolymer with C-N, N-H, and O-H groups.
· O/W emulsion preparation: SDS (0.5 g) was dissolved in 300 g H2O containing resorcinol and NaCl (variable ratios). The solution was heated to 60°C, mixed with 15 g n-tetradecane, and emulsified at 1500 rpm (60°C, 30 min) to form an o/w emulsion. Condensation (CH2OH and NH groups) initiated upon adjusting the emulsion pH to 3-4.
· Nanocapsule fabrication: The prepolymer was dripped into the emulsion under 200 rpm stirring. The pH was adjusted to 3-4 with 40% formic acid, maintaining 60°C. Stirring was increased to 500 rpm for 4 h to form a urea-formaldehyde shell encapsulating n-tetradecane. The nanocapsules were filtered, washed thrice with 70°C H2O, and vacuum-dried for 20 h.

Preparation of Tetradecane Nanoemulsion via Low-Energy Emulsification Method

Schalbart, P., et al. International journal of refrigeration, 2010, 33(8), 1612-1624.

In comparison to traditional single-phase heat transfer fluids like chilled water used in air conditioning, phase change emulsions significantly enhance apparent specific heat within their phase change temperature range. This advancement presents valuable opportunities for improving heat transfer, as well as thermal energy transport and storage.
Nanoemulsions of tetradecane in water have been successfully created using a blend of non-ionic surfactants (Tween60 and Span60). Various emulsification techniques were explored to achieve these nanoemulsions. The low-energy emulsification methods, such as the phase inversion temperature approach, highlighted the critical role of crossing the inversion line and the rate of that transition. By employing the most suitable method, emulsions were generated with a narrow droplet size distribution of 200 to 250 nm.
These emulsions demonstrated stability against sedimentation and creaming for over six months, along with low viscosity values ranging from 2 to 4 times that of water. However, Ostwald ripening led to slight droplet size growth and a decrease in viscosity.
Various property measurements and analyses showed promising results, with the possibility of increasing the apparent heat capacity. The table 4 summarized the optimal emulsification method alongside the properties of the developed nanoemulsion. Thermal analyses revealed promising characteristics for utilizing phase change nanoemulsions in thermal storage and transport applications.

Custom Q&A

What is the molecular formula of tetradecane?

The molecular formula of tetradecane is C14H30.

What is the molecular weight of tetradecane?

The molecular weight of tetradecane is 198.39 g/mol.

What is the IUPAC name of tetradecane?

The IUPAC name of tetradecane is tetradecane.

What is the InChI of tetradecane?

The InChI of tetradecane is InChI=1S/C14H30/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3-14H2,1-2H3.

What is the InChIKey of tetradecane?

The InChIKey of tetradecane is BGHCVCJVXZWKCC-UHFFFAOYSA-N.

What is the canonical SMILES of tetradecane?

The canonical SMILES of tetradecane is CCCCCCCCCCCCCC.

What is the CAS number of tetradecane?

The CAS number of tetradecane is 629-59-4.

What is the XLogP3 value of tetradecane?

The XLogP3 value of tetradecane is 7.2.

How many rotatable bonds does tetradecane have?

Tetradecane has 11 rotatable bonds.

What is the topological polar surface area of tetradecane?

The topological polar surface area of tetradecane is 0Ų.