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Catalog Number
ACM865485
Product Name
Sodium tert-butoxide
Structure
CAS
865-48-5
Synonyms
sodiumt-butoxide,stb;sodiumt-butoxide,stb,in;sodiumt-butoxide,stb,intetrahydrofuran;sodium 2-methylpropan-2-olate;SODIUM TERTIARY BUTOXIDE;SODIUM TERT-BUTOXIDE;SODIUM TERT-BUTYLATE;SODIUM T-BUTOXIDE
Molecular Formula
C4H9NaO
Molecular Weight
96.1
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1 Chemoselective Coupling of 1,1-Bis[(pinacolato)boryl]alkanes for the Transition-Metal-Free Borylation of Aryl and Vinyl Halides: A Combined Experimental and Theoretical Investigation.

Lee Y1, Baek SY2,3, Park J1, Kim ST2,3, Tussupbayev S2,3, Kim J1, Baik MH2,3, Cho SH1.

J Am Chem Soc. 2016 Dec 30. doi: 10.1021/jacs.6b11757. [Epub ahead of print]

A new transition-metal-free borylation of aryl and vinyl halides using 1,1-bis[(pinacolato)boryl]alkanes as boron sources is described. In this transformation one of the boron groups from 1,1-bis[(pinacolato)boryl]alkanes is selectively transferred to aryl and vinyl halides in the presence of sodium tert-butoxide as the only activator to form organoboronate esters. Under the developed borylation co ... Read More

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Contact us

Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA