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Carravetta M1, Concistre M1, Levason W1, Reid G1, Zhang W1.
Inorg Chem. 2016 Dec 19;55(24):12890-12896. Epub 2016 Nov 23.
Reaction of Me2PCH2CH2PMe2 or o-C6H4(PMe2)2 (L-L) with a suspension of ScI3 or YI3 in MeCN solution under rigorously anhydrous and oxygen-free conditions produced the highly unusual complexes [ScI3(L-L)2], [YI3(Me2PCH2CH2PMe2)2], and [YI3{o-C6H4(PMe2)2}2MeCN]. X-ray crystal structures reveal that the scandium complexes adopt seven-coordinate, pentagonal-bipyramidal geometries with chelating diphosp ... Read MoreProducts
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