(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%

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Catalog Number
ACM573718566
Product Name
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%
CAS
573718-56-6
Category
Heterocyclic Organic Compound
Synonyms
573718-56-6;MFCD09264281;[Rh COD (R)-P-Phos]BF4;[Rh COD (S)-P-Phos]BF4;(R )-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine(1,5-cyclooctadiene)rhodium(I) BF4;(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3,3'-BIPYRIDINE(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE;(S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine(1,5-cyclooctadiene)rhodium(I) BF4;[(R)-4,4'-Bis(diphenylphosphino)-2,2',6,6'-tetramethoxy-3,3'-bipyridine](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;[(S)-4,4'-Bis(diphenylphosphino)-2,2',6,6'-tetramethoxy-3,3'-bipyridine](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate;
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;[3-(4-diphenylphosphanyl-2,6-dimethoxypyridin-3-yl)-2,6-dimethoxypyridin-4-yl]-diphenylphosphane;rhodium;tetrafluoroborate;
Molecular Weight
942.541g/mol
Molecular Formula
C46H46BF4N2O4P2Rh-;
Canonical SMILES
[B-](F)(F)(F)F.COC1=NC(=C(C(=C1)P(C2=CC=CC=C2)C3=CC=CC=C3)C4=C(N=C(C=C4P(C5=CC=CC=C5)C6=CC=CC=C6)OC)OC)OC.C1CC=CCCC=C1.[Rh];
InChI
InChI=1S/C38H34N2O4P2.C8H12.BF4.Rh/c1-41-33-25-31(45(27-17-9-5-10-18-27)28-19-11-6-12-20-28)35(37(39-33)43-3)36-32(26-34(42-2)40-38(36)44-4)46(29-21-13-7-14-22-29)30-23-15-8-16-24-30;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h5-26H,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;;
InChI Key
JGBGWKDXLJSPBK-ONEVTFJLSA-N;
Application
Chiral ligand for enantioselective rhodium-catalyzed [2+2+2] carbocyclization reactions.

Chiral ligand for the asymmetric hydrogenation of β-keto esters.

Highly enantioselective hydrogenation of β-alkyl-substituted (E)-β-(acylamino)-acrylates
Complexity
863
Covalently-Bonded Unit Count
4
Defined Bond Stereocenter Count
2
Exact Mass
942.202g/mol
Formal Charge
-1
H-Bond Acceptor
11
Heavy Atom Count
60
Monoisotopic Mass
942.202g/mol
Rotatable Bond Count
11
Topological Polar Surface Area
62.7A^2
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