Tris(N,N-bis(trimethylsilyl)amide)lanthanum(III), min. 98% (99.9%-La) (REO)

CAS

175923-07-6

Catalog Number

ACM175923076

Category

Micro/NanoElectronics

Molecular Weight

620.066g/mol

Molecular Formula

C18H54LaN3Si6;

MSDS COA Spec Sheet

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Specification

Synonyms

Silanamine,1,1,1-trimethyl-N-(trimethylsilyl)-, lanthanum(3+) salt (3:1); Lanthanum tris[trimethyl-N-(trimethylsilyl)silanaminide]; 175923-07-6; LANTHANUM TRIS(HEXAMETHYLDISILAZIDE); bis(trimethylsilyl)azanide; AC1O1C9N; DTXSID30421941; Tris[bis(trimethylsilyl)amino] lanthanum;

IUPAC Name

bis(trimethylsilyl)azanide;lanthanum(3+);

Canonical SMILES

C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.C[Si](C)(C)[N-][Si](C)(C)C.[La+3];

InChI

InChI=1S/3C6H18NSi2.La/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3;

InChI Key

ZDYNTRMQDURVDM-UHFFFAOYSA-N;

Application

Catalyst precursor for enantioselective intramolecular hydroamination of aminoalkenes and aminodienes.

Catalyzes a mild and highly selective addition of terminal alkynes to nitriles to form conjugated ynones.

Catalytic amidation of aldehydes with amines.

Complexity

76.2

Covalently-Bonded Unit Count

Exact Mass

619.2g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

619.2g/mol

Rotatable Bond Count

Topological Polar Surface Area

3A^2