tert-Butyldiphenylsilane

• CAS: 33729-92-9
• Catalog Number: ACM33729929
• Category: Silylation Reagents
• Molecular Weight: 240.42
• Molecular Formula: C16H20Si
• Synonyms: tert-Butyldiphenylsilane, 33729-92-9, ACMC-209i2e, CTK4H1125, ANW-27684, AG-L-22978
• IUPAC Name: tert-butyl(diphenyl)silane
• InChI Key: VTORJPDWMOIOIQ-UHFFFAOYSA-N
• Boiling Point: 103 °C(0.05 mmHg)
• Appearance: Colorless to almost colorless clear liquid
• Storage: Store under inert gas
• Exact Mass: 240.13300
• Hazard Statements: H315 : Causes skin irritation.; H319 : Causes serious eye irritation.
• H-Bond Acceptor: 0
• H-Bond Donor: 0
• MDL Number: MFCD05663906
• Packaging: 5 g
• Physical State: Liquid
• Precautionary Statements: P264 : Wash skin thoroughly after handling.; P280 : Wear protective gloves/ eye protection/ face protection.; P302 + P352 : IF ON SKIN: Wash with plenty of water.; P337 + P313 : If eye irritation persists: Get medical advice/ attention.; P362 + P364 : Take off contaminated clothing and wash it before reuse.; P332 + P313 : If skin irritation °Ccurs: Get medical advice/ attention.
• PubChem ID: 125307247
• Signal Word: Warning
• Specific Gravity: 0.97

Synthetic Use

Downstream Synthesis Route 1

• 33729-92-9

• 58479-61-1

Reference: [1] Organometallics, 2012, vol. 31, # 8, p. 3199 - 3206
[2] Journal of the American Chemical Society, 1952, vol. 74, p. 5091,5094,5095

Downstream Synthesis Route 2

• 1493-13-6
• 33729-92-9

• 136839-64-0

Reference: [1]Uhlig, Wolfram
[Chemische Berichte, 1992, vol. 125, # 1, p. 47 - 54]

Downstream Synthesis Route 3

• 33729-92-9
• 114114-39-5

• 114114-40-8

Reference: [1]Sviridov, A. F.; Ermolenko, M. S.; Yashunsky. D. V.; Borodkin, V. S.; Kochetkov, N. K.
[Tetrahedron Letters, 1987, vol. 28, # 33, p. 3835 - 3838]
[2]Sviridov, A. F.; Ermolenko, M. S.; Yashunskii, D. V.; Borodkin, V. S.; Kochetkov, N. K.
[Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 1989, vol. 38, # 2.2, p. 382 - 391][Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1989, # 2, p. 438 - 447]

* For details of the synthesis route, please refer to the original source to ensure accuracy.