T-Butyldimethylsilane

• CAS: 29681-57-0
• Catalog Number: ACM29681570
• Category: Alkyl Silane
• Molecular Weight: 116.28 g/mol
• Molecular Formula: C6H16Si
• Synonyms: tert-ButyldimethylsilaneButyldimethylsilaneTert-Butyl(Dimethyl)Silyl
• IUPAC Name: tert-butyl(dimethyl)silicon
• Canonical SMILES: CC(C)(C)[Si](C)C
• InChI Key: ILMRJRBKQSSXGY-UHFFFAOYSA-N
• Boiling Point: 82.697 °C(760 mmHg)
• Flash Point: -22.778 °C
• Density: 0.701 g/mLat25°C(lit.)
• Appearance: Liquid
• Application: T-Butyldimethylsilane serves multiple purposes in chemical synthesis and protection processes. It is prominently used for protecting hydroxy groups in sugars, a vital step in carbohydrate chemistry. Additionally, its oxidation product, tert-butyldimethylsilyl hydroperoxide, aids in creating luminescent sources and prostanoids such as clavulons. In catalyst chemistry, T-Butyldimethylsilane reacts with an iridium complex to form an active catalyst for the regioselective silylation of various methyl hexopyranosides and related compounds. Furthermore, when used in silylcarbobicyclization reactions with certain catalysts under carbon monoxide pressure, it yields innovative 2-silylbicyclo[3.3.0]octa-1,5-dien-3-ones, demonstrating its versatile role in advancing synthetic methodologies.
• Exact Mass: 116.10200
• Hazard Statements: F,Xi
• Packaging: 10 g; 100 g
• Safety Description: S16-S26-S36

Custom Q&A

What is the molecular formula of t-Butyldimethylsilane?

The molecular formula is C6H15Si.

What is the molecular weight of t-Butyldimethylsilane?

The molecular weight is 115.27 g/mol.

What is the InChIKey of t-Butyldimethylsilane?

The InChIKey is ILMRJRBKQSSXGY-UHFFFAOYSA-N.

What is the Canonical SMILES of t-Butyldimethylsilane?

The Canonical SMILES is CC(C)(C)[Si](C)C.

What is the CAS number of t-Butyldimethylsilane?

The CAS number is 29681-57-0.

What is the European Community (EC) number of t-Butyldimethylsilane?

The EC number is 627-972-4.

What is the hydrogen bond donor count of t-Butyldimethylsilane?

The hydrogen bond donor count is 0.

What is the hydrogen bond acceptor count of t-Butyldimethylsilane?

The hydrogen bond acceptor count is 0.

How many rotatable bonds are there in t-Butyldimethylsilane?

There is 1 rotatable bond in t-Butyldimethylsilane.

What is the topological polar surface area of t-Butyldimethylsilane?

The topological polar surface area is 0Ų.