(R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, min. 97%

• CAS: 619334-93-9
• Catalog Number: ACM619334939
• Category: Other Products
• Molecular Weight: 986.769g/mol
• Molecular Formula: C56H62BF4P2Rh-
• Synonyms: [Rh COD (S)-Xyl-Phanephos]BF4; 619334-93-9; [(R)-4,12-Bis[di(3,5-xylyl)phosphino][2.2]paracyclophane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; [Rh COD (R)-Xyl-Phanephos]BF4; [(S)-4,12-Bis[di(3,5-xylyl)phosphino][2.2]paracyclophane](1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
• IUPAC Name: [11-bis(3,5-dimethylphenyl)phosphanyl-5-tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaenyl]-bis(3,5-dimethylphenyl)phosphane;(1Z,5Z)-cycloocta-1,5-diene;rhodium;tetrafluoroborate
• SMILES: [B-](F)(F)(F)F.CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=C4CCC5=CC(=C(CCC(=C3)C=C4)C=C5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C.C1CC=CCCC=C1.[Rh]
• InChI: InChI=1S/C48H50P2.C8H12.BF4.Rh/c1-31-17-32(2)22-43(21-31)49(44-23-33(3)18-34(4)24-44)47-29-39-9-13-41(47)15-11-40-10-14-42(16-12-39)48(30-40)50(45-25-35(5)19-36(6)26-45)46-27-37(7)20-38(8)28-46;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h9-10,13-14,17-30H,11-12,15-16H2,1-8H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-
• InChI Key: APILCLFERIYDHA-ONEVTFJLSA-N
• Application: Catalyst for the enantioselective hydrogenation of unsaturated amino acid derivatives.
• Complexity: 973
• Covalently-Bonded Unit Count: 4
• Defined Bond Stereocenter Count: 2
• Exact Mass: 986.341g/mol
• Formal Charge: -1
• H-Bond Acceptor: 5
• Heavy Atom Count: 64
• Monoisotopic Mass: 986.341g/mol
• Rotatable Bond Count: 6
• Topological Polar Surface Area: 0A^2

Custom Reviews

December 15, 2022

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This reagent works great!
I did have a chance to try this reagent in my experiment, which gave me a great result in my experiment. I would definitely consider to use it in my future experiments.