Phenyl-[(R)-1,1'-spirobiindane-7,7'-diyl]-phosphite((R)-ShiP)

• Catalog Number: ACM656233533
• Product Name: Phenyl-[(R)-1,1'-spirobiindane-7,7'-diyl]-phosphite((R)-ShiP)
• CAS: 656233-53-3
• Category: Heterocyclic Organic Compound
• Synonyms: AB1005807; (R)-ShiP; AKOS015950895; Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,10,11,12,13-tetrahydro-5-phenoxy-,(11ar)-; (aR)-7,7'-(Phenoxyphosphinidenebisoxy)-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]; (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy; (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1|I,7|I-fg][1,3,2]dioxaphosphocin-5-phenoxy; 885701-71-3; Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite; 7,7'-(Phenoxyphosphinidenebisoxy)-1,1'-spirobiindan
• IUPAC Name: 12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine
• Molecular Weight: 374.376g/mol
• Molecular Formula: C23H19O3P
• Canonical SMILES: C1CC23CCC4=C2C(=CC=C4)OP(OC5=CC=CC1=C35)OC6=CC=CC=C6
• InChI: InChI=1S/C23H19O3P/c1-2-8-18(9-3-1)24-27-25-19-10-4-6-16-12-14-23(21(16)19)15-13-17-7-5-11-20(26-27)22(17)23/h1-11H,12-15H2
• InChI Key: JVANYVSBBJFGMW-UHFFFAOYSA-N
• Application: Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.; ; Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.; ; Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.; ; Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.; ; Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.
• Complexity: 510
• Covalently-Bonded Unit Count: 1
• Exact Mass: 374.107g/mol
• H-Bond Acceptor: 3
• Heavy Atom Count: 27
• Monoisotopic Mass: 374.107g/mol
• Rotatable Bond Count: 2
• Topological Polar Surface Area: 27.7A^2