Methyl-2,3-o-isopropylidene-beta-D-riboFuranoside

• CAS: 4099-85-8
• Catalog Number: ACM4099858
• Category: Other Products
• Molecular Weight: 204.22
• Molecular Formula: C9H16O5
• Synonyms: 2,3-O-Isopropylidene-B-D-ribofuranoside
• IUPAC Name: [(3aR,4R,6R,6aR)-4-methoxy-2,2-dimethyl-3a,4,6,6a-tetrahydrofuro[3,4-d][1,3]dioxol-6-yl]methanol
• SMILES: CC1(O[C@@H]2[C@H](O[C@H]([C@@H]2O1)OC)CO)C
• InChI: InChI=1S/C9H16O5/c1-9(2)13-6-5(4-10)12-8(11-3)7(6)14-9/h5-8,10H,4H2,1-3H3/t5-,6-,7-,8-/m1/s1
• InChI Key: DXBHDBLZPXQALN-WCTZXXKLSA-N
• Density: 1.23±0.1 g/ml
• Appearance: Clear yellow oil
• pKa: 14.14±0.10

Synthetic Use

Upstream Synthesis Route 1

• 67-56-1
• 532-20-7
• 67-64-1

• 4099-85-8

Reference: [1] Synthesis (Germany), 2017, vol. 49, # 18, p. 4299 - 4302

Upstream Synthesis Route 2

• 50-69-1
• 77-76-9
• 67-64-1

• 4099-85-8

Reference: [1] Patent: US2004/6007, 2004, A1, . Location in patent: Page/Page column 18; sheet 2

Upstream Synthesis Route 3

• 67-56-1
• 50-69-1
• 77-76-9

• 4099-85-8

Reference: [1] Journal of medicinal chemistry, 2001, vol. 44, # 18, p. 2966 - 2975
[2] Patent: JP2015/205885, 2015, A, . Location in patent: Paragraph 0443; 0444
[3] Organic Letters, 2007, vol. 9, # 6, p. 1121 - 1124

Upstream Synthesis Route 4

• 50-69-1
• 77-76-9
• 67-64-1

• 4099-85-8

Reference: [1]Patent: US2004/6007,2004,A1 .Location in patent: Page/Page column 18; sheet 2

Downstream Synthesis Route 1

• 4099-85-8

• 54622-95-6

Reference: [1]Chemistry - A European Journal,2006,vol. 12,p. 5246 - 5252

Downstream Synthesis Route 2

• 4099-85-8
• 98-59-9

• 4137-56-8

Reference: [1]Sarabia-Garcia, Francisco; Lopez-Herrera, F. Jorge
[Tetrahedron, 1996, vol. 52, # 13, p. 4757 - 4768]

* For details of the synthesis route, please refer to the original source to ensure accuracy.