Structure

Hydride Q Resin

CAS
68988-57-8
Catalog Number
ACM68988578-3
Category
Main Products
Molecular Weight
0
Molecular Formula
C8H20O4Si.C2H7ClSi

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Specification

Synonyms
Dimethylchlorosilane,ethylsilicatehydrolysisproduct;silicicacid(h4sio4),tetraethylester,reactionproductswithchlorodimethyls;silicicacid(h4sio4),tetraethylester,reactionproductswithchlorodimethylsilane;Silicicacid,tetraethylester,reactionproductswithchlorodimethylsilane;HYDRIDE Q RESIN;HYDRIDE Q RESIN, VISCOSITY 3-5 CST.;HYDRIDE Q RESIN: VISCOSITY 6-8 CST.;HYDRIDE Q RESIN, 3-5cs
IUPAC Name
chloro(dimethyl)silicon;tetraethylsilicate
SMILES
CCO[Si](OCC)(OCC)OCC.C[Si](C)Cl
InChI Key
DGGWFOAMZZNWAV-UHFFFAOYSA-N
Density
0,94 g/cm³
Appearance
Clear liquid
EC Number
273-531-0
Packaging
10 g; 100 g;
Viscosity
3-5 cst

Hydride Q Resin for the Synthesis of Oligosiloxanes with Mesogenic Groups

Schematic diagram of the synthesis scheme of mesogenic oligomers with Hydride Q Resin as the core. Ahsan, Md Shameem, et al. Reactive and Functional Polymers 67.11 (2007): 1200-1210.

Researchers produced oligosiloxanes with mesogenic groups using hydrosilylation catalyzed by Karstedt's catalyst. These utilized cores with distinct structures: tetrakis(dimethylsiloxy)silane (A, cross), 1,3,5,7-tetramethylcyclotetrasiloxane (B, cubic), tetraphenyltetrahydroxycyclotetrasiloxane (C, cyclic, bulky phenyl), tetrakis(dimethylsilyl)octaphenylsilsesquioxane (D, double-decker), and hydride Q resin (E, branched) with distinct core structures. The researchers used mesogenic derivatives including 4-allyloxy-4'-cyanobiphenyl (M1) and cholesteryl-10-undecenoate (M2) in their experiments. The investigation of phase behaviors in structurally diverse oligomers showed that nearly all compounds demonstrated liquid crystalline properties over a wide temperature spectrum.
Synthesis of Mesogenic Oligomers (Example: CM1):
Compound C (0.51 g, 0.65 mmol) and M1 (0.75 g, 3.19 mmol) were mixed under dry nitrogen. Toluene (15 ml) and Pt-divinyltetramethyldisiloxane catalyst (10 μl) were added, followed by stirring for 1 h. The solution was evaporated to dryness. The crude product was purified by column chromatography (Wako Gel C-300, eluted sequentially with toluene and chloroform) and reprecipitated in methanol. Product purity (CM1: 1,3,5,7-tetraphenyl-1,3,5,7-tetrakis(dimethylsiloxy)cyclotetrasiloxane with M1) was confirmed by HPLC. Yield = 46%.
Synthesis of EM1:
EM1 (Hydride Q resin with M1) was synthesized similarly. Purification employed the same column chromatography and methanol reprecipitation. Yield = 39%.

What is the molecular formula of Hydride Q resin?

The molecular formula of Hydride Q resin is C10H26ClO4Si2.

What is the molecular weight of Hydride Q resin?

The molecular weight of Hydride Q resin is 301.93 g/mol.

What are some synonyms of Hydride Q resin?

Some synonyms of Hydride Q resin include 68988-57-8, EINECS 273-531-0, and MFCD01323580.

What is the parent compound of Hydride Q resin?

The parent compound of Hydride Q resin is Tetraethyl orthosilicate.

What are the component compounds of Hydride Q resin?

The component compounds of Hydride Q resin are Tetraethyl orthosilicate and Chlorodimethylsilane.

When was Hydride Q resin created?

Hydride Q resin was created on March 7, 2015.

When was Hydride Q resin last modified?

Hydride Q resin was last modified on October 21, 2023.

What is the InChI of Hydride Q resin?

The InChI of Hydride Q resin is InChI=1S/C8H20O4Si.C2H6ClSi/c1-5-9-13(10-6-2,11-7-3)12-8-4;1-4(2)3/h5-8H2,1-4H3;1-2H3.

What is the InChIKey of Hydride Q resin?

The InChIKey of Hydride Q resin is DGGWFOAMZZNWAV-UHFFFAOYSA-N.

What is the physical description of Hydride Q resin?

Hydride Q resin is a liquid.

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