2,2'-Bis(diphenylphosphino)biphenyl

• Catalog Number: ACM84783642
• Product Name: 2,2'-Bis(diphenylphosphino)biphenyl
• CAS: 84783-64-2
• Category: Organic Phosphine Compounds
• Synonyms: BIPHEP; MFCD03094574; AKOS015911364; DB-009479; 1,1'-[[1,1'-BIPHENYL]-2,2'-DIYL]BIS[1,1-DIPHENYL]-PHOSPHINE; CTK3J1519; SCHEMBL1120987; 2,2'-Bis(diphenylphosphino)biphenyl; 2,2'-bis(diphenylphosphanyl)-1,1'-biphenyl; FT-0657577
• IUPAC Name: [2-(2-diphenylphosphanylphenyl)phenyl]-diphenylphosphane
• Molecular Weight: 522.568g/mol
• Molecular Formula: C36H28P2
• Canonical SMILES: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3C4=CC=CC=C4P(C5=CC=CC=C5)C6=CC=CC=C6
• InChI: InChI=1S/C36H28P2/c1-5-17-29(18-6-1)37(30-19-7-2-8-20-30)35-27-15-13-25-33(35)34-26-14-16-28-36(34)38(31-21-9-3-10-22-31)32-23-11-4-12-24-32/h1-28H
• InChI Key: GRTJBNJOHNTQBO-UHFFFAOYSA-N
• Application: Supporting ligand in a chiral diamine-ruthenium system for the enantioselective hydrogenation of ketones.; ; Useful ligand for palladium-catalyzed amination and Kumada cross-coupling reactions; ; Useful ligand for palladium-catalyzed synthesis of butatrenes.; ; Useful ligand for iridium-catalyzed C-C cross-coupling of allenes with primary alcohols via transfer hydrogenation.; ; Useful ligand for iridium-catalyzed C-C cross-coupling of dienes with primary alcohols via transfer hydrogenation.; ; Useful ligand for iridium-catalyzed C-C cross-coupling of allylic gem-dicarboxylates with aldehydes via transfer hydrogenation.; ; Useful ligand for the palladium-catalyzed synthesis of chiral allenylsilanes.; ; Ruthenium-catalyzed synthesis of indoles.; ; Ruthenium-catalyzed oxidative cyclization.; ; Rhodium-catalyzed boron arylation.
• Complexity: 573
• Covalently-Bonded Unit Count: 1
• Exact Mass: 522.167g/mol
• Heavy Atom Count: 38
• Monoisotopic Mass: 522.167g/mol
• Rotatable Bond Count: 7
• Topological Polar Surface Area: 0A^2